1007604-36-5Relevant academic research and scientific papers
Practical, scalable, high-throughput approaches to η3- pyranyl and η3-pyridinyl organometallic enantiomeric scaffolds using the achmatowicz reaction
Coombs, Thomas C.,Lee IV, Maurice D.,Wong, Heilam,Armstrong, Matthew,Cheng, Bo,Chen, Wenyong,Moretto, Alessandro F.,Liebeskind, Lanny S.
, p. 882 - 888 (2008)
(Figure Presented) A unified strategy for the high-throughput synthesis of multigram quantities of the η3-oxopyranyl- and η3-oxopyridinylmolybdenum complexes TpMo(CO)2(η 3-oxopyranyl) and TpMo(CO)2(η3- oxopyridinyl) is described (Tp = hydridotrispyrazolylborato). The strategy uses the oxa- and aza-Achmatowicz reaction for the preparation of these organometallic enantiomeric scaffolds, in both racemic and high enantiopurity versions.
