100897-38-9Relevant articles and documents
Rearrangement of Chloromethylphosphinidene into Methylenechlorophosphine in the Co-ordination Sphere of Tungsten. Stabilization of an Unhindered P=C Double Bond without Deactivation by ?-Complexation
Deschamps, Bernard,Mathey, Francois
, p. 1010 - 1012 (1985)
Transient rearranges into stable (η2-CH2=PCl)W(CO)5 which can be characterized in solution by i.r., (1)H n.m.r., and (31)P n.m.r. spectroscopy and reacts readily with alcohols and conjugated dienes as a ?-P-co-ordinated species.