Rearrangement of Chloromethylphosphinidene into Methylenechlorophosphine in the Co-ordination Sphere of Tungsten. Stabilization of an Unhindered P=C Double Bond without Deactivation by ?-Complexation

DOI: 10.1039/c39850001010

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1010 - 1012 (1985)

Update date:2022-08-04

Topics:

Authors:

Deschamps, Bernard

Mathey, Francois

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39850001010

Transient rearranges into stable (η²-CH2=PCl)W(CO)5 which can be characterized in solution by i.r., (1)H n.m.r., and (31)P n.m.r. spectroscopy and reacts readily with alcohols and conjugated dienes as a ?-P-co-ordinated species.

Full text of DOI:10.1039/c39850001010

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:W(CO)5(PC₅H₆(C₆H₅)2(Cl))

Cas No:100897-38-9

R&D Labs maybe for 100897-38-9

Reliable Pharma Technology (Shanghai) Co., Ltd.

Contact:0086-21-67676847-8008

Address:Lane 1500, No.68, Xinfei Road, Songjiang District, Shanghai, 201611, P.R.China.
Shanggao Ruiya Fine Chemicals Co., Ltd

Contact:+86-795-2592103

Address:Xingguang Nanlu,Shanggao County Industry Park
shandong zhongke taidou chemical co.,ltd

Contact:86-531-88682301

Address:Jinan shandong Province CHina
TIANJIN NORTH JINHENG CHEMICAL PLANT.

Contact:0086-22-59952083

Address:DongShigu Country In JiXian TianJin China
Hunan Zhongqi Pharmaceutical Co., Ltd

website:http://www.hnzqzy.com

Contact:0730-8722288 13807308622

Address:Wanjiafan Road ,Yueyang Economic And Technological Development Zone ,Hunan,PRC

Relevant to this article

The Role and Nature of the Radical Anion Intermediates in Electron Transfer Catalysis of Bicapped Tri-iron Clusters

Doi:10.1039/c39860000121
(1986)
An efficient approach to the stereoselective synthesis of 2,6-disubstituted dihydropyrans via stannyl-Prins cyclization

Doi:10.1016/j.tetlet.2007.11.128
(2008)
Synthesis and antiprotozoal activities of simplified analogs of naphthylisoquinoline alkaloids

Doi:10.1016/j.ejmech.2007.03.003
(2008)
Biarylalkyl Carboxylic Acid Derivatives as Novel Antischistosomal Agents

Doi:10.1002/cmdc.201600127
(2016)
Obtaining symmetric and asymmetric bisphosphoramidates and bisphosphoramidothioates by a single step multicomponent reaction

Doi:10.1080/10426507.2021.1878358
(2021)
Chiral N-phosphoryl imines: Design, synthesis and direct asymmetric addition reactions with diketones and diesters

Doi:10.1016/j.tetlet.2010.06.072
(2010)

Article Doi