Rearrangement of Chloromethylphosphinidene into Methylenechlorophosphine in the Co-ordination Sphere of Tungsten. Stabilization of an Unhindered P=C Double Bond without Deactivation by ?-Complexation

DOI: 10.1039/c39850001010

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1010 - 1012 (1985)

Update date:2022-08-04

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Authors:

Deschamps, Bernard

Mathey, Francois

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Article abstract of DOI:10.1039/c39850001010

Transient rearranges into stable (η²-CH2=PCl)W(CO)5 which can be characterized in solution by i.r., (1)H n.m.r., and (31)P n.m.r. spectroscopy and reacts readily with alcohols and conjugated dienes as a ?-P-co-ordinated species.

Full text of DOI:10.1039/c39850001010

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Product name:W(CO)5(PC₅H₆(C₆H₅)2(Cl))

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