10095-29-1Relevant academic research and scientific papers
Cycloaddition reactions of benzynes generated from benzobisoxadisilole, benzotrisoxadisilole and naphthoxadisilole
Chen, Ya-Li,Zhang, Hong-Kui,Wong, Wai-Yeung,Lee, Albert W.M
, p. 2259 - 2262 (2002)
Benzynes (7, 16) generated from benzobisoxadisilole and benzotrisoxadisilole were trapped as the furan cycloaddition adducts. Naphthoxadisilole and naphthobisoxadisilole were also synthesized.
Copper-Free Double Silylation of 1,2-Dibromobenzenes Using a Mg/LiCl/DMI System
Kitamura, Tsugio,Yamada, Rin,Gondo, Keisuke,Eguchi, Nobuo,Oyamada, Juzo
, p. 2495 - 2500 (2017/05/22)
The reaction of 1,2-dibromobenzenes with chlorotrimethylsilane efficiently proceeded in the presence of Mg and LiCl in DMI under mild conditions, giving 1,2-bis(trimethylsilyl)benzenes in good to high yields. The reaction of 1,2-dibromobenzenes with chlorodimethylsilane under the same conditions afforded the corresponding 1,2-bis(dimethylsilyl)benzenes in high yields. Functional group transformations of 1,2-bis(trimethylsilyl)benzene were conducted to demonstrate the synthetic utility.
Nanosized starlike molecules. Synthesis and optical properties of tris- and tetrakis[oligo(disilanylenebithienylene)dimethylsilyl]benzene
Naka, Akinobu,Matsumoto, Yoshiaki,Itano, Tatsuya,Hasegawa, Kei,Shimamura, Tomoaki,Ohshita, Joji,Kunai, Atsutaka,Takeuchi, Takae,Ishikawa, Mitsuo
scheme or table, p. 346 - 352 (2009/04/13)
The syntheses of two types of starlike molecules with the arms that extend to three and four directions have been reported. The molecules with the arms consisting of a regular alternating arrangement of a silicon-silicon bond and bithienylene unit that ex
Generation of synthetic equivalents of benzdiynes from benzobisoxadisiloles
Chen, Ya-Li,Sun, Jiang-Qin,Wei, Xin,Wong, Wai-Yeung,Lee, Albert W. M.
, p. 7190 - 7197 (2007/10/03)
Linear and angular benzobisoxadisiloles 14 and 16 can serve as the precursors for stepwise generations of the syntetic equivalents of 1,4- and 1,3-benzdiynes. Benzynes generated were trapped as [4+2] cycloaddition products. Two identical or different ring
