100991-97-7Relevant academic research and scientific papers
Synthesis of ethyl (13E)-trifluoromethylretinoate and its analogues by palladium-catalysed cross-coupling
Thibonnet, Jerome,Prie, Gildas,Abarbri, Mohamed,Duchene, Alain,Parrain, Jean-Luc
, p. 3151 - 3154 (1999)
Stereoselective construction of ethyl (13E)-trifluoromethylretinoate was achieved through two successive Stille reactions. The coupling of (E)-1,2- bis(tributylstannyl)ethene and ethyl (Z)-4,4,4-trifluoro-3-iodobut-2-enoate was performed first and followe
Stereocontrolled synthesis of retinoids functionalized at C-13 by Suzuki coupling reactions
Alvarez, Rosana,Iglesias, Beatriz,De Lera, Angel R.
, p. 13779 - 13790 (2007/10/03)
The retinal analogues (13Z)-13-bromo- 13-desmethylretinal (3) and (13E)- 20,20,20-trifluororetinal (4) have been efficiently synthesized using the palladium-catalyzed cross-coupling of boronic acid 8 and electrophiles 9 and 10, respectively. For the first
PREPARATION OF 20,20,20-TRIFLUORORETINAL(13-TRIFLUOROMETHYLRETINAL)
Hanzawa, Yuji,Kawagoe, Kei-ichi,Kobayashi, Nobuo,Oshima, Toshihide,Kobayashi, Yoshiro
, p. 2877 - 2880 (2007/10/02)
All-trans-20,20,20-trifluororetinal (1) was prepared by two ways.
