Synthesis of ethyl (13E)-trifluoromethylretinoate and its analogues by palladium-catalysed cross-coupling

DOI: 10.1016/S0040-4039(99)00414-1

Source and publish data:

Tetrahedron Letters p. 3151 - 3154 (1999)

Update date:2022-08-11

Topics:

Authors:

Thibonnet, Jerome

Prie, Gildas

Abarbri, Mohamed

Duchene, Alain

Parrain, Jean-Luc

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Article abstract of DOI:10.1016/S0040-4039(99)00414-1

Stereoselective construction of ethyl (13E)-trifluoromethylretinoate was achieved through two successive Stille reactions. The coupling of (E)-1,2- bis(tributylstannyl)ethene and ethyl (Z)-4,4,4-trifluoro-3-iodobut-2-enoate was performed first and followe

Full text of DOI:10.1016/S0040-4039(99)00414-1

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