101003-65-0

Basic information

• Product Name: 4'-HYDROXY-2,2':6',2''-TERPYRIDINE
• Synonyms: 4'-HYDROXY-2,2':6',2''-TERPYRIDINE;2,6-dipyridin-2-yl-1H-pyridin-4-one
• CAS NO: 101003-65-0
• Molecular Formula: C15H11N3O
• Molecular Weight: 249.27
• Mol File: 101003-65-0.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 505.5 °C at 760 mmHg
• Flash Point: 259.5 °C
• Appearance: /
• Density: 1.269 g/cm³
• PKA: 8.76±0.18(Predicted)
• CAS DataBase Reference: 4'-HYDROXY-2,2':6',2''-TERPYRIDINE(CAS DataBase Reference)
• NIST Chemistry Reference: 4'-HYDROXY-2,2':6',2''-TERPYRIDINE(101003-65-0)
• EPA Substance Registry System: 4'-HYDROXY-2,2':6',2''-TERPYRIDINE(101003-65-0)

Safety Data

• Hazardous Substances Data: 101003-65-0(Hazardous Substances Data)

Usage

General Description

4'-HYDROXY-2,2':6',2''-TERPYRIDINE is a chemical compound that belongs to the class of terpyridines, which are organic compounds containing three pyridine rings. It is a derivative of terpyridine with an additional hydroxyl group attached to the fourth position of one of the pyridine rings. This chemical has potential applications in the fields of coordination chemistry, materials science, and medicinal chemistry due to its unique structural and electronic properties. It can also serve as a ligand for metal ions and be involved in the synthesis of coordination complexes for various purposes. Additionally, the hydroxyl group on the terpyridine molecule can potentially be involved in hydrogen bonding interactions with other molecules, further expanding its potential applications in various chemical and biological processes.

Upstream product

• 1122-62-9 2-acetylpyridine 
• 616-38-6 carbonic acid dimethyl ester 
• 1678-15-5 1,5-di-pyridin-3-yl-pentane-1,3,5-trione 
• 128143-87-3 1,5-bis(2′-pyridyl)pentane-1,3,5-trione 
• 2524-52-9 ethyl-2-picolinate 

Downstream Products

• 741264-92-6 4’-[phenylethynyl]-2,2’:6’,2’’-terpyridine 
• 128143-89-5 4'-Chloro-2,2':6',2''-terpyridine 

Relevant articles and documents

Cobalt bis(2-ethylhexanoate) and terpyridine derivatives as catalysts for the hydrosilylation of olefins

A simple method for the hydrosilylation of olefins by using air-stable cobalt catalysts is developed. The catalyst system is composed of simple, cheap, and readily available cobalt(II) salts and well-defined terpyridine derivatives as cocatalysts or ligands, and the hydrosilylation processes can be processed smoothly under mild conditions without either Grignard reagents or NaHBEt3 as activator.

Gelation properties of terpyridine gluconic acid derivatives and their reversible stimuli-responsive white light emitting solution

Two gluconic acid derivatives C3 and C6 bearing a terpyridyl moiety were designed and synthesized. Thanks to the hydrophilic interaction from glucosyl moiety, C3 and C6 can dissolve in polar solvents and gel aromatic solvents with a critical gel concentration of weight 1.5%. The solution consisting of organic ligand C3 as sensitizer and Ln(III) ions as emitters can realize white light emission with thermo- and chemical stimuli-response properties in luminescence spectra. Further, the self-assemblies of C3 and C6 were examined by the combination of the theoretical calculations via hybrid density functional theory (DFT) with 1H nuclear magnetic resonance (1HNMR) and powder X-ray diffraction (PXRD) analysis. The study actually provides a reliable method for the formation of potential functional smart materials.