101015-59-2

Basic information

• Product Name: 3--1.2-benzo-3.4-cyclohexan-cyclobuten-(1)
• Synonyms: 3--1.2-benzo-3.4-cyclohexan-cyclobuten-(1)
• CAS NO: 101015-59-2
• Molecular Weight: 227.349
• Mol File: 101015-59-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3--1.2-benzo-3.4-cyclohexan-cyclobuten-(1)(CAS DataBase Reference)
• NIST Chemistry Reference: 3--1.2-benzo-3.4-cyclohexan-cyclobuten-(1)(101015-59-2)
• EPA Substance Registry System: 3--1.2-benzo-3.4-cyclohexan-cyclobuten-(1)(101015-59-2)

Safety Data

• Hazardous Substances Data: 101015-59-2(Hazardous Substances Data)

Upstream product

• 1072-85-1 o-fluorobromobenzene 
• 1125-99-1 1-(1-Cyclohexen-1-yl)pyrrolidine 

Relevant articles and documents

Reactions of Enamines with Dehydro Aromatic Compounds

Benzyne reacts with enamines through a combination of ene and 2 + 2 cycloadditions.One of the two possible ene reactions is greatly favored.The three-dimensional intermediate, 1,2-dehydro-o-carborane, eschews the 2 + 2 reaction in favor of the ene reaction that is less favored in the benzyne reactions.This preference is rationalized in terms of the different steric demands of the two intermediates.