Journal of Organic Chemistry p. 3803 - 3806 (1992)
Update date:2022-09-26
Topics:
Gingrich, Henry L.
Huang, Qiurong
Morales, Angel L.
Jones, Maitland
Benzyne reacts with enamines through a combination of ene and 2 + 2 cycloadditions.One of the two possible ene reactions is greatly favored.The three-dimensional intermediate, 1,2-dehydro-o-carborane, eschews the 2 + 2 reaction in favor of the ene reaction that is less favored in the benzyne reactions.This preference is rationalized in terms of the different steric demands of the two intermediates.
View MoreContact:0572-2722882
Address:1201,F3,xinghuibandao,
website:http://www.chinabarton.com
Contact:+86-573-82719618
Address:No. 162 Fumin Road, Honghe Town,
Suzhou Ryan Pharmachem Technology Co.,Ltd
Contact:+86-0512-68780025
Address:B-301,No.2 Taishan Road,Suzhou New District,Jiangsu,P.R. China
Wuhan Jadechem International Trade Co.,Ltd.
website:http://www.jadechem-intl.com
Contact:+86-27-83527060
Address:Room 502,Building C11,Software new city No.8,Huacheng Avenue,East Lake High-tech development zone,Wuhan,Hubei,China
website:https://www.sinoshiny.com/products
Contact:+86-20-62802632;62802633
Address:Room 330 GIGCAS Building,No.511 Kehua Street,Tianhe District
Doi:10.1021/acs.orglett.0c02190
(2020)Doi:10.1080/00958972.2017.1394460
(2017)Doi:10.1021/ja01601a057
(1956)Doi:10.1021/ja01608a031
(1955)Doi:10.1021/jo00078a014
(1993)Doi:10.1021/jo01112a021
(1956)
