Journal of Organic Chemistry p. 3803 - 3806 (1992)
Update date:2022-09-26
Topics:
Gingrich, Henry L.
Huang, Qiurong
Morales, Angel L.
Jones, Maitland
Benzyne reacts with enamines through a combination of ene and 2 + 2 cycloadditions.One of the two possible ene reactions is greatly favored.The three-dimensional intermediate, 1,2-dehydro-o-carborane, eschews the 2 + 2 reaction in favor of the ene reaction that is less favored in the benzyne reactions.This preference is rationalized in terms of the different steric demands of the two intermediates.
View MoreContact:+91 - 22 - 26355700
Address:17, Lotus Business Park, Andheri West
Shanghai Mio Chemical Co., Ltd
Contact:0086 21- 64401188-622
Address:16 Floor NO.2 Jiefang Building, No. 4855 Dushi Road, 201100 Shanghai, P.R.China
Hangzhou Donglou Bio-nutrient Co., Ltd.
Contact:+86-571-82225795,13967112289
Address:Louta Town, Xiaoshan,Hangzhou,Zhejiang
Zibo Ocean International Trade Co.,Ltd(expird)
Contact:+86 533 5160706
Address:1117, Hongtai Bld., Songling rd, Zichuan,Zibo,Shandong,China
ShiJiaZhuang Dowell Chemical Co.,Ltd.
website:http://www.dowechem.com
Contact:+86-13463963265
Address:Xiyangling village, high tech Zone, Shijiazhuang，Hebei, China
Doi:10.1021/acs.orglett.0c02190
(2020)Doi:10.1080/00958972.2017.1394460
(2017)Doi:10.1021/ja01601a057
(1956)Doi:10.1021/ja01608a031
(1955)Doi:10.1021/jo00078a014
(1993)Doi:10.1021/jo01112a021
(1956)
