101089-41-2

Basic information

• Product Name: C₁₅H₁₅NO
• Synonyms: C₁₅H₁₅NO
• CAS NO: 101089-41-2
• Molecular Weight: 225.29
• Mol File: 101089-41-2.mol
• Article Data: 17

Chemical Properties

• CAS DataBase Reference: C₁₅H₁₅NO(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₅H₁₅NO(101089-41-2)
• EPA Substance Registry System: C₁₅H₁₅NO(101089-41-2)

Safety Data

• Hazardous Substances Data: 101089-41-2(Hazardous Substances Data)

Upstream product

• 2001-28-7 2-phenyl-1-p-tolyl-ethanone 
• 108-88-3 toluene 
• 103-80-0 phenylacetyl chloride 
• 103-82-2 phenylacetic acid 
• 99-75-2 4-methyl-benzoic acid methyl ester 
• 5720-05-8 4-methylphenylboronic acid 
• 140-29-4 phenylacetonitrile 

Downstream Products

• 1629159-50-7 2-phenyl-3-(p-tolyl)-2H-azirine 
• 138073-16-2 dimethyl 2-phenyl-5-(p-tolyl)-1H-pyrrole-3,4-dicarboxylate 

Relevant articles and documents

Copper-Catalyzed Three-Component Carboboronation of Allenes Using Highly Strained Cyclic Ketimines as Electrophiles

A diastereoselective copper and NHC-ligand-catalyzed three-component difunctionalization of allenes with bis(pinacolato)diboron and 2H-azirines to afford borylated allylaziridines is described. The reaction exhibits complete diastereoselectivity and good yields, and the further chlorination of the corresponding borylated products was also performed. It is believed that the high ring-strain force of 2H-azirines facilitates the reaction. More chemical transformations of borylated allylaziridines are also reported.

Ruthenium-Catalyzed [3 + 2] Cycloaddition of 2H-Azirines with Alkynes: Access to Polysubstituted Pyrroles

A ruthenium-catalyzed intermolecular [3 + 2] cycloaddition of 2H-azirines and activated alkynes is reported, which provides polysubstituted pyrroles in moderate to good yields. This approach features a C-N bond cleavage of 2H-azirines by a ruthenium catal

The organocatalytic enantiodivergent fluorination of β-ketodiaryl-phosphine oxides for the construction of carbon-fluorine quaternary stereocenters

Commercially available cinchona alkaloids that can catalyze the enantiodivergent fluorination of β-ketodiarylphosphine oxides were developed to construct carbon-fluorine quaternary stereocenters. This protocol features a wide scope of substrates and excellent enantioselectivities, and it is scalable.