101089-46-7

Basic information

• Product Name: 1-Butanone, 1-phenyl-4-(4-pyridinyl)-
• CAS NO: 101089-46-7
• Molecular Formula: C15H15NO
• Molecular Weight: 225.29
• Mol File: 101089-46-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1-Butanone, 1-phenyl-4-(4-pyridinyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Butanone, 1-phenyl-4-(4-pyridinyl)-(101089-46-7)
• EPA Substance Registry System: 1-Butanone, 1-phenyl-4-(4-pyridinyl)-(101089-46-7)

Safety Data

• Hazardous Substances Data: 101089-46-7(Hazardous Substances Data)

Upstream product

• 100-43-6 4-vinylpyridine 
• 94-02-0 ethyl 3-oxo-3-phenylpropionate 
• 98-86-2 acetophenone 
• 70-11-1 α-bromoacetophenone 

Downstream Products

• 847946-85-4 4-(4-phenyl-cis-but-3-enyl)-pyridine 
• 896155-85-4 C₁₉H₂₂N₂O 

Relevant articles and documents

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Modulation of the reactivity, stability and substrate- and enantioselectivity of an epoxidation catalyst by noncovalent dynamic attachment of a receptor functionality - Aspects on the mechanism of the Jacobsen-Katsuki epoxidation applied to a supramolecular system

The synthesis of the components of the dynamic supramolecular hydrogen-bonded catalytic system 2 + 3 is described. The catalytic performance and substrate- and enantioselectivity of Mn(salen) catalyst 2 were investigated in the presence and absence of the Zn(porphyrin) receptor unit 3. The effects of pyridine and pyridine N-oxide donor ligands were also studied. Some aspects on the mechanism of the Jacobsen-Katsuki epoxidation, based on literature observations, are introduced as a means to analyse the behaviour of 2 and its modulation by the formation of macrocycle 1 with 3. A complete association model of the metal-free system 4 + 5 refutes the earlier assumption that macrocycle 1 is the predominant form of catalyst 2 under the standard epoxidation reaction conditions with 2 + 3. Evidence are provided that receptor-binding substrates and nonbinding substrates, respectively, are epoxidised by two different catalytic species, or two distinct distributions of species in competitive epoxidations using catalytic system 2 + 3. The two species are assigned to the endo and exo faces of the Mn(salen) catalyst in macrocycle 1, and to equivalently folded oligomeric structures with monomers 2 and 3 in adjacent positions. The Royal Society of Chemistry 2006.