1011458-53-9

Basic information

• Product Name: ethyl 2-[(5-chloro-2-methoxycarbonylmethyl)phenyl]-2-(phenylthio)acetate
• Synonyms: ethyl 2-[(5-chloro-2-methoxycarbonylmethyl)phenyl]-2-(phenylthio)acetate
• CAS NO: 1011458-53-9
• Molecular Weight: 378.876
• Mol File: 1011458-53-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: ethyl 2-[(5-chloro-2-methoxycarbonylmethyl)phenyl]-2-(phenylthio)acetate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl 2-[(5-chloro-2-methoxycarbonylmethyl)phenyl]-2-(phenylthio)acetate(1011458-53-9)
• EPA Substance Registry System: ethyl 2-[(5-chloro-2-methoxycarbonylmethyl)phenyl]-2-(phenylthio)acetate(1011458-53-9)

Safety Data

• Hazardous Substances Data: 1011458-53-9(Hazardous Substances Data)

Upstream product

• 52449-43-1 (4-chloro-phenyl)-acetic acid methyl ester 
• 108-98-5 thiophenol 
• 7605-25-6 ethyl phenylsulfenylacetate 
• 93961-29-6 methyl 2-(4-chlorophenyl)-2-diazoacetate 

Relevant articles and documents

Photochemical, Metal-Free Sigmatropic Rearrangement Reactions of Sulfur Ylides

Sigmatropic rearrangement reactions constitute one of the most fundamental reactions of carbenes. While state-of-the-art synthetic methods require the use of expensive precious metal catalysts, the application of visible light for the photolysis of α-aryldiazoacetates is much less investigated and provides an operationally simple entry to carbenes under mild reaction conditions. Herein, we report on blue-light induced sigmatropic rearrangement reactions of sulfur compounds with α-aryldiazoacetates. This process, depending on the substitution pattern of the sulfide, opens up formal insertion reactions of carbenes into S?N, S?C, or C?H bonds.