101471-67-4Relevant academic research and scientific papers
A Synthesis of Seco-mesembrane Alkaloids, (+/-)-Joubertiamine, (+/-)-Joubertinamine, and (+/-)-Epijoubertinamine
Hoshino, Osamu,Ishizaki, Miyuki,Sawaki, Shohei,Yuasa, Masayuki,Umezawa, Bunsuke
, p. 3373 - 3380 (2007/10/02)
A synthesis of seco-mesembrane alkaloids, (+/-)-joubertiamine (4), (+/-)-joubertinamine (5), and (+/-)-epijoubertinamine (6), was accomplished starting with 2-allyl-2-aryl-5,5-ethylenedioxycyclohexanones (10 and 3), which are readily available by allylati
A Concise Synthetic Route to Polyfunctional γ-Ketoester Derivatives via Methoxy(phenylthio)methyl-lithium
Hackett, Steven,Livinghouse, Tom
, p. 75 - 76 (2007/10/02)
The α,β-unsaturated O,S-acetals obtained via the reaction of methoxyphenylthiomethyl-lithium with 3-alkoxyenones are readily convertible into structurally diverse γ-ketoesters by way of an efficient alkylation-hydrolysis sequence.
