99706-75-9

Upstream product

• 13865-50-4 methoxymethyl phenyl sulfide 
• 85907-71-7 3-(dimethylamino)-2-(3,4-dimethoxyphenyl)prop-2-en-1-al 
• 57788-49-5 methoxy(phenylthio)methane lithium 
• 108-98-5 thiophenol 

Downstream Products

• 102737-69-9 4-(3,4-Dimethoxy-phenyl)-4-((E)-2-methoxy-2-phenylsulfanyl-vinyl)-cyclohex-2-enone 
• 99706-79-3 4-(3,4-dimethoxyphenyl)-4-<(Z)-2-methoxy-2-(phenylthio)vinyl>cyclohex-2-en-1-one 
• 99706-78-2 4-(3,4-dimethoxyphenyl)-4-<(E)-2-methoxy-2-(phenylthio)vinyl>cyclohex-2-en-1-one 
• 101471-67-4 4-(carbomethoxymethyl)-4-(3,4-dimethoxyphenyl)cyclohex-2-en-1-one 
• 21104-34-7 N-methyl-3a-<3,4-(dimethoxy)phenyl>-2,3,3a,4,5,6,7,7a-octahydroindole-2,6-dione 

Relevant academic research and scientific papers

lithium and lithium. Convenient Reagents for the Facile Conversion of Aldehydes, Ketones, and 3-Alkoxy Enones into Ketene O,S-Acetal Derivatives

The title organometalics have been found to react in the 1,2-sense with a variety of carbonyl compounds to provide O,S-acetal and ketene O,S-acetal derivatives in high yield.The β,γ-unsaturated O,S-acetals obtained via the reaction of methoxy(phenylthio)

A Concise Synthetic Route to Polyfunctional γ-Ketoester Derivatives via Methoxy(phenylthio)methyl-lithium

The α,β-unsaturated O,S-acetals obtained via the reaction of methoxyphenylthiomethyl-lithium with 3-alkoxyenones are readily convertible into structurally diverse γ-ketoesters by way of an efficient alkylation-hydrolysis sequence.