101574-68-9Relevant articles and documents
Regioselective synthesis of N-acetylureas by manganese(III) acetate reaction of 1,3-disubstituted thioureas
Mu, Xue-Jun,Zou, Jian-Ping,Qian, Qiu-Feng,Zhang, Wei
, p. 2323 - 2325 (2006)
Reactions of asymmetrical 1,3-disubstituted thioureas with manganese(III) acetate produce regioselective N-acetylureas. A mechanism for this novel transformation is proposed.
Hypervalent iodine(III)-mediated regioselective N-acylation of 1,3-disubstituted thioureas
Singh,Ghosh, Harisadhan,Murru, Siva,Patel, Bhisma K.
, p. 2924 - 2927 (2008/09/19)
(Chemical Equation Presented) Reaction of asymmetrical 1,3-disubstituted thioureas with diacetoxyiodobenzene (DIB) produces regioselectively N-acetylurea in shorter time. Regioselectivity is dependent on the pKa's of the amine attached to the t