101584-01-4Relevant articles and documents
Synthesis of α-heterosubstituted ketones through sulfur mediated difunctionalization of internal alkynes
Zhang, Zhong,Luo, Yuzheng,Du, Hongguang,Xu, Jiaxi,Li, Pingfan
, p. 5156 - 5161 (2019/06/05)
Synthesis of α-heterosubstituted ketones was achieved through sulfur mediated difunctionalization of internal alkynes in one pot. The reaction design involves: phenyl substituted internal alkyne attacking triflic anhydride activated diphenyl sulfoxide to
Heteroannulation of arynes with N-aryl-α-aminoketones for the synthesis of unsymmetrical N-aryl-2,3-disubstituted indoles: An aryne twist of Bischler-Moehlau indole synthesis
Bunescu, Ala,Piemontesi, Cyril,Wang, Qian,Zhu, Jieping
supporting information, p. 10284 - 10286 (2013/10/22)
Reaction of 2-(trimethylsilyl)aryl triflates 1 with N-aryl-α-amino ketones 2 afforded N-aryl-2,3-disubstituted indoles in good to excellent yields with complete control of the substitution patterns. This methodology allowed for the first time a one-step s