1016225-14-1Relevant articles and documents
Remarkable levels of enantioswitching in catalytic asymmetric hydroboration
Smith, Sean M.,Takacs, James M.
scheme or table, p. 4612 - 4615 (2010/12/19)
TADDOL-derived phosphites and phosphoramidites are effective ligands for rhodium-catalyzed asymmetric hydroborations of β,γ-unsaturated amides, achieving up to 99% ee. However, the sense of stereoinduction, R or S, is surprisingly dependent on rather subt
Nonenzymatic kinetic resolution of 3-hydroxyalkanamides with chiral copper catalyst
Demizu, Yosuke,Kubo, Yuki,Matsumura, Yoshihiro,Onomura, Osamu
, p. 433 - 437 (2008/09/16)
Kinetic resolution of 3-hydroxyalkanamides with good to high selectivities was achieved by benzoylation using copper(II) triflate and (R,R)-PhBox [2,2′-isopropylidenebis(4-phenyl-2-oxazoline)] as catalyst, which also mediated enantioselective tosylation o