101703-83-7Relevant articles and documents
Desymmetrization of meso-1,2-diols via chiral Lewis acid-mediated ring-cleavage of 1,3-dioxolane derivatives
Kinugasa,Harada,Oku
, p. 9067 - 9068 (1997)
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Asymmetric desymmetrization of saturated and unsaturated meso-1,2-diols
Fujioka, Hiromichi,Nagatomi, Yasushi,Kotoku, Naoyuki,Kitagawa, Hidetoshi,Kita, Yasuyuki
, p. 10141 - 10151 (2007/10/03)
An asymmetric desymmetrization of saturated and unsaturated cyclic and acyclic meso-1,2-diols has been developed from the ene acetals, prepared from the norbornene carboxyaldehyde and meso-1,2-diols. The intramolecular haloetherification of the ene acetals as a key step afforded 8-membered acetals in a stereoselective manner just by the reaction of norbornene olefin even when the ene acetals from unsaturated meso-1,2-diols having olefins in the same molecule were used. Subsequent reductive elimination, followed by protecting the hydroxy group and transacetalization, gave optically active 1,2-diol derivatives and the starting ene acetals in good yields. (C) 2000 Elsevier Science Ltd.
The chemistry of L-ascorbic and D-isoascorbic acids. I. The preparation of chiral butanetriols and -tetrols
Abushanab,Vemishetti,Leiby,Singh,Mikkilineni,Wu,Saibaba,Panzica
, p. 2598 - 2602 (2007/10/02)
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