101874-45-7Relevant articles and documents
A novel C-H insertion via deoxygenation of amides by a Sm/SmI2 mixed system
Ogawa, Akiya,Takami, Noriaki,Nanke, Taizoh,Ohya, Syoji,Hirao, Toshikazu,Sonoda, Noboru
, p. 12895 - 12902 (1997)
A samarium/samarium diiodide mixed system successfully effects novel aminocyclopropanation and C-H insertion via the deoxygenation of amides. Styrenes undergo aminocyclopropanation by the reaction with aromatic amides, samarium metal, and samarium diiodide. Furthermore, the reaction of aliphatic amides with Sm/SmI2 in the presence of alkylbenzenes like toluene causes benzylic C-H insertion giving the corresponding phenylethylamine derivatives in good yields.
A New Method for the Synthesis of α-Substituted Phenethylamines via Titanium Amide Complexes
Takahashi, Hiroshi,Tsubuki, Takeshi,Higashiyama, Kimio
, p. 238 - 240 (2007/10/02)
Substituted phenethylamines (1-substituted 2-phenylethylamines) 4 are obtained in high yields by a new, facile reaction of titanium amide complexes with aldehydes and benzylmagnesium chloride.