10192-58-2Relevant academic research and scientific papers
Thallium(III) oxide as an oxidative reagent in organic chemistry
Gun'kin
, p. 451 - 454 (2010/08/04)
Oxidative properties of thallium(III) oxide in various organic reactions were studied. Oxidative bromination of organic compounds in Tl2O 3-KBr-trifluoroacetic acid system was carried out. New synthetic method for preparation of diphenylthallium salts from phenylhydrazine and thallium(III) oxide was developed.
Organothallium compounds. Reaction of phenylhydrazine with thallium(III) oxide
Gun'kin
, p. 824 - 825 (2007/10/03)
Phenylhydrazine reacts with thallium(III) oxide in benzene to give organothallium compounds. Reactions of these compounds with acids afford diphenylthallium salts.
Synthesis of Diphenylthallium Acetate and Bromide from Phenylhydrazine and Thallium(III) Oxide
Gun'kin
, p. 21 - 22 (2007/10/03)
A new procedure for synthesis of diphenylthallium acetate and bromide was developed, involving reaction of phenylhydrazine with thallium(III) oxide to give organothallium compounds. Certain factors affecting this reaction were studied.
Organothallium compounds. Mechanistic study of the disproportionation reaction of organothallium compounds with copper in acetonitrile
Gun'kin, I. F.
, p. 1887 - 1890 (2007/10/02)
Disproportionation reactions of various phenyl- and thienylthallium dicarboxylates with copper in acetonitrile have been carried out.The reaction mechanism proposed involves the participation of the ArTl2+ dication and various pairs of the dica
