101981-08-2

Upstream product

• 81221-80-9 4-(bromomethyl)tetradecachlorotriphenylmethyl radical 
• 105-53-3 diethyl malonate 
• 101998-20-3 6,6'-((4-(bromomethyl)-2,3,5,6-tetrachlorophenyl)methylene)bis(1,2,3,4,5-pentachlorobenzene) 

Downstream Products

• 101981-10-6 4-(2-(alaninocarbonyl)ethyl)tetradecachlorotriphenylmethyl radical ethyl ester 
• 101981-09-3 tetradecachloro-4-(2-(chlorocarbonyl)ethyl)triphenylmethyl radical 
• 101981-05-9 4-(2-carboxyethyl)tetradecachlorotriphenylmethyl radical 

Relevant academic research and scientific papers

Inert Carbon Free Radicals. 7. "The (Kinetic) Reverse Effect" and Relevant Synthesis of New Monofunctionalized Triphenylmethyl Radicals and Their Nonradical Counterparts

The high chemical passivity of the so-called "inert free radicals" (IFRs), particularly those derived from perchlorotriphenylmethyl (PTM), has allowed one to ascertain the kinetic influence of the free radical character on the reactivity of their nonradic

The Influence of a Substituent with Free Radical Character (Reverse Effect) on Some Nucleophilic Substitutions involving Benzylic Systems

The free radical character of the benzyl bromide (1) causes accelerations in the nucleophilic substitution reactions with acetate and with diethyl malonate anions which are interpreted in terms of a change-transfer, biradical configuration for the SN2 transition state.