1020741-86-9Relevant academic research and scientific papers
Gold(I)/(III)-catalyzed rearrangement of divinyl ketones and acyloxyalkynyloxiranes into cyclopentenones
Hoffmann, Marie,Weibel, Jean-Marc,De Fremont, Pierre,Pale, Patrick,Blanc, Aurelien
supporting information, p. 908 - 911 (2014/03/21)
Multifaceted gold(I/III) catalysts with their carbophilic and oxophilic characters catalyzed very efficiently the formation of hydroxylated cyclopentenones from simple divinyl ketones or acyloxyalkynyloxiranes. The Nazarov reaction is rapidly performed in
Gold(I)-catalyzed rearrangement of alkynloxiranes: A mild access to divinyl ketones
Cordonnier, Marie-Caroline,Blanc, Aurlien,Pale, Patrick
supporting information; experimental part, p. 1569 - 1572 (2009/04/07)
Acyloxylated divinyl ketones are conveniently formed by a new gold(l)-catalyzed rearrangement of (3-acyloxyprop-1-ynyl)oxiranes.
