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102078-57-9

p-chlorophenyl(phenyl)methyl p-tolyl sulfone is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 102078-57-9 Structure

  • Basic information

    1. Product Name: p-chlorophenyl(phenyl)methyl p-tolyl sulfone
    2. Synonyms: p-chlorophenyl(phenyl)methyl p-tolyl sulfone
    3. CAS NO:102078-57-9
    4. Molecular Formula:
    5. Molecular Weight: 356.873
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 102078-57-9.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: p-chlorophenyl(phenyl)methyl p-tolyl sulfone(CAS DataBase Reference)
    10. NIST Chemistry Reference: p-chlorophenyl(phenyl)methyl p-tolyl sulfone(102078-57-9)
    11. EPA Substance Registry System: p-chlorophenyl(phenyl)methyl p-tolyl sulfone(102078-57-9)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 102078-57-9(Hazardous Substances Data)

102078-57-9 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 102078-57-9 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,0,2,0,7 and 8 respectively; the second part has 2 digits, 5 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 102078-57:
(8*1)+(7*0)+(6*2)+(5*0)+(4*7)+(3*8)+(2*5)+(1*7)=89
89 % 10 = 9
So 102078-57-9 is a valid CAS Registry Number.

102078-57-9Downstream Products

102078-57-9Relevant articles and documents

Substrate- and temperature-controlled divergence in reactions of alcohols with TosMIC catalyzed by BF3 · Et2O: Facile access to sulfinates and sulfones

Pogaku, Naresh,Krishna, Palakodety Radha,Prapurna, Y. Lakshmi

, p. 1239 - 1249 (2017/07/06)

An efficient BF3 · Et2O-catalyzed divergent synthesis of sulfinate esters and sulfones through C–O and C–S bond formation has been achieved from alcohols and p-toluenesulfonylmethyl isocyanide (TosMIC). Various alcohols reacted smoothly with TosMIC under the present conditions at room temperature providing sulfinate esters exclusively. By tuning the reaction temperature, the alcohols that provide highly stabilized carbocation in the reaction medium afforded sulfones as sole products. This study was aimed at understanding the regioselectivity of ambidentate sulfinate ion and to elucidate the interpretation of sulfinate/sulfone scaffolds.

Arylative Desulfonation of Diarylmethyl Phenyl Sulfone with Arenes Catalyzed by Scandium Triflate

Nambo, Masakazu,Ariki, Zachary T.,Canseco-Gonzalez, Daniel,Beattie, D. Dawson,Crudden, Cathleen M.

supporting information, p. 2339 - 2342 (2016/06/09)

A scandium-triflate-catalyzed arylative desulfonation of diarylmethyl phenyl sulfones with arenes and heteroarenes was established. A variety of both sulfone and arene substrates were reacted to afford symmetric and nonsymmetric triarylmethanes in good yields. Further transformations of the resulting triarylmethanes and application to the concise synthesis of a bactericidal agent analogue were also demonstrated.

Direct sulfonylation of Baylis-Hillman alcohols and diarylmethanols with TosMIC in ionic liquid-[Hmim]HSO4: An unexpected reaction

Garima,Srivastava, Vishnu P.,Yadav, Lal Dhar S.

experimental part, p. 4622 - 4626 (2011/09/21)

A Bronsted acidic ionic liquid-[Hmim]HSO4 promoted unexpected reaction of Baylis-Hillman alcohols and diarylmethanols with p-toluenesulfonylmethyl isocyanide (TosMIC) affording the corresponding sulfone derivatives instead of N-tosylmethyl amid

Palladium-catalyzed benzylic direct arylation of benzyl sulfones with aryl halides

Niwa, Takashi,Yorimitsu, Hideki,Oshima, Koichiro

experimental part, p. 1971 - 1976 (2009/08/07)

An effective palladium catalyst system for the direct arylation of benzyl sulfones with aryl halides has been developed. The catalytic reaction provides a facile route to diarylmethyl sulfones. The products can be transformed further via desulfonylative functionalization mediated by aluminum compounds.

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