102184-00-9

Basic information

• Product Name: phenyl phenanthrene-9-carboxylate
• Synonyms: phenyl phenanthrene-9-carboxylate
• CAS NO: 102184-00-9
• Molecular Weight: 298.341
• Mol File: 102184-00-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: phenyl phenanthrene-9-carboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: phenyl phenanthrene-9-carboxylate(102184-00-9)
• EPA Substance Registry System: phenyl phenanthrene-9-carboxylate(102184-00-9)

Safety Data

• Hazardous Substances Data: 102184-00-9(Hazardous Substances Data)

Upstream product

• 16605-99-5 biphenyl-2-carboxylic acid methyl ester 
• 947-84-2 2-Biphenylcarboxylic acid 
• 108-95-2 phenol 
• 1005-56-7 phenylcarbonochloridothioate 
• 1271739-74-2 O-(9-phenanthryl) O-phenyl thiocarbonate 
• 16331-54-7 phenanthrene-9-carbonyl chloride 

Downstream Products

• 121787-54-0 phenyl(10-phenylphenanthren-9-yl)methanonephenyl(10-phenylphenanthren-9-yl)methanone 
• 67961-32-4 phenylindenophenanthrene 
• 122335-90-4 phenyl-(10-phenyl-9,10-dihydro-[9]phenanthryl)-ketone 

Relevant articles and documents

Remote and Selective C(sp2)-H Olefination for Sequential Regioselective Linkage of Phenanthrenes

Biphenylcarboxylic acid with two competing C(sp2)-H sites was designed for site selective C(sp2)-H functionalization by developing carboxylic acids assisted remote and selective olefination via 7-membered palladacycle. Mechanism investigation and DFT calculations reveal a kinetics-determined process, which could be utilized to explore a variety of remote site selectivity. The practicability of this method was highlighted by the precise construction of phenathrene under sequential site selectivity.

DIRECT CONVERSION OF PHENOLS INTO AMIDES AND ESTERS OF BENZOIC ACID

A method is provided for the preparation of an aromatic carboxylic acid aryl ester or an N-aryl aromatic carboxamide. The method comprises contacting an O,O-diaryl thiocarbonate or an O-aryl-N-aryl thiocarbamate with a reactant that regioselectively reacts with sulfur, which contact causes an O-neophyl rearrangement, thereby forming either the aromatic carboxylic acid aryl ester or the N-aryl aromatic carboxamide, respectively.