10219-30-4Relevant academic research and scientific papers
Practical catalytic method for synthesis of sterically hindered anilines
Mailig, Melrose,Rucker, Richard P.,Lalic, Gojko
supporting information, p. 11048 - 11051 (2015/07/07)
A practical catalytic method for the synthesis of sterically hindered anilines is described. The amination of aryl and heteroaryl boronic esters is accomplished using a catalyst prepared in situ from commercially available and air-stable copper(i) triflat
Copper-catalyzed N- tert -butylation of aromatic amines under mild conditions using tert -butyl 2,2,2-trichloroacetimidate
Cran, John W.,Vidhani, Dinesh V.,Krafft, Marie E.
, p. 1550 - 1554 (2014/07/08)
A variety of aromatic amines have been found to expediently undergo copper-catalyzed N-tert-butylation in the presence of tert-butyl 2,2,2-trichloroactimidate at room temperature. Georg Thieme Verlag Stuttgart New York.
An unusual radical smiles rearrangement
Bacque, Eric,El Qacemi, Myriem,Zard, Samir Z.
, p. 3817 - 3820 (2007/10/03)
(Chemical Equation Presented) Radicals derived from N-(α-xanthyl) acetanilides or N-(α-xanthyl)acetylaminopyridines possessing a substituent next to the nitrogen undergo a hitherto undocumented Smiles rearrangement proceeding through a four-membered ring.
Para-bromination of ortho-alkyl anilines
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, (2008/06/13)
A process of selectively preparing p-bromo-o-alkylanilines (e.g. 4-bromo-2-methylaniline) by reacting o-alkylanilines (e.g., 2-methylaniline) with unadsorbed bromine in a solvent selected from the group consisting of an inert di- tri- or tetrahaloaliphatic hydrocarbon (e.g., dichloromethane and dibromomethane), an alkyl nitrile (e.g., acetonitrile) and mixtures thereof.
