51339-03-8

Basic information

• Product Name: N-(tert-butyl)-O-benzoylhydroxylamine
• Synonyms: N-(tert-butyl)-O-benzoylhydroxylamine
• CAS NO: 51339-03-8
• Molecular Weight: 193.246
• Mol File: 51339-03-8.mol
• Article Data: 11

Chemical Properties

• CAS DataBase Reference: N-(tert-butyl)-O-benzoylhydroxylamine(CAS DataBase Reference)
• NIST Chemistry Reference: N-(tert-butyl)-O-benzoylhydroxylamine(51339-03-8)
• EPA Substance Registry System: N-(tert-butyl)-O-benzoylhydroxylamine(51339-03-8)

Safety Data

• Hazardous Substances Data: 51339-03-8(Hazardous Substances Data)

Upstream product

• 16649-50-6 N-tert-Butylhydroxylamine 
• 98-88-4 benzoyl chloride 
• 75-64-9 tert-butylamine 
• 94-36-0 dibenzoyl peroxide 

Downstream Products

• 79894-26-1 N-Benzoyloxy-N-tert-butyl-2-methylsulfanyl-benzamide 
• 83859-62-5 N-acetyl-O-benzoyl-N-t-butylhydroxylamine 
• 774-65-2 benzoic acid tert-butyl ester 
• 115-11-7 isobutene 
• 41979-47-9 N-tert-butyl-1,1-diphenylphosphinamine 
• 57377-16-9 N-(4-methylphenylsulfinyl)-N-(tert-butyl)amine 
• 36171-07-0 4-bromo-N-(tert-butyl)aniline 
• 40686-52-0 N-(tert-butyl)-4-iodoaniline 
• 10219-30-4 N-(tert-butyl)-2-methylaniline 
• 16649-50-6 N-tert-Butylhydroxylamine 
• 280137-56-6 N-tert-butyl-N-{N'-[[(9-fluorenylmethyl)oxy]carbonyl]-L-alanoyl}-O-benzoylhydroxylamine 
• 280137-55-5 N-tert-butyl-N-{N'-[[(9-fluorenylmethyl)oxy]carbonyl]-glycinoyl}-O-benzoylhydroxylamine 
• 92844-61-6 N-tert-butyl-N-nitro-O-benzoylhydroxylamine 

Relevant articles and documents

Electron paramagnetic resonance studies on the generation and solvation of n-heptafluoropropyl t-butyl nitroxide

n-Heptafluoropropyl t-butyl nitroxide (3) has been generated by the use of the electron-transfer reaction of O-benzoyl-N-t-butylhydroxylamine (1) and heptafluorobutyryl peroxide (2) in CFCl2CF2Cl solution.Electron paramagnetic resonance (EPR) measurements

Rhodium(III)-catalyzed C–H amination of 2-arylquinazolin-4(3H)-one with N-alkyl-O-benzoyl-hydroxylamines

N-benzoate alkylamines were used as the aminating agents, a efficient Rh-catalyzed ortho C–H amination of 2-arylquinazolin-4(3H)-one has been reported. The reactions exhibit high efficient and good functional group tolerance. Exclusive 2,6-bis-aminated pr

New highly efficient method for the synthesis of tert-alkyl nitroso compounds

The syntheses of tert-alkyl nitroso compounds RCH2CMe 2N=O from commercially available tert-alkyl amines RCH 2CMe2NH2 proceed cleanly via the intermediacy of the benzoyl derivatives RCH2CMe2NHOC(O)Ph and the corresponding hydroxylamines RCH2CMe2NHOH. Since the intermediates require no purification in the course of the transformations, the overall yields of the isolated crystalline nitroso dimers (75-80% for R = H, 75% for R = Me and 66% for R = Me3C) are based on the corresponding amine precursors. In the latter case (R = Me3C), significant steric demands and hydrophobicity of Me3CCH2CMe2 group necessitate the application of more efficient reagents and conditions on the debenzoylation and oxidation steps. The syntheses are perfectly suitable for scale-up and were successfully performed on up to 500-mmol scale. Georg Thieme Verlag Stuttgart.