102208-56-0Relevant academic research and scientific papers
Stereoselectivity of Electrophile-Promoted Cyclizations of γ-Hydroxyalkenes. An Investigation of Carbohydrate-Derived and Model Substrates
Reitz, Allen B.,Nortey, Samuel O.,Maryanoff, Bruce E.,Liotta, Dennis,Robert, Monahan
, p. 4191 - 4202 (2007/10/02)
We have investigated cyclization reactions of γ-hydroxyalkenes bearing an alkoxy or alkyl substituent on the allylic carbon.A variety of electrophiles N-bromosuccinimide, N-iodosuccinimide, iodine, mercury(II) acetate, mercury(II) trifluoroacetate, mercu
STEREOSELECTIVITY IN THE ELECTROPHILE-MEDIATED CYCLIZATION OF 2,3,5-TRI-O-BENZYL-1,2-DIDEOXY-D-arabino-HEX-1-ENITOL. A STEREOCONTROLLED SYNTHESIS OF 1-AMINO-2,5-ANHYDRO-3,4,6-TRI-O-BENZYL-1-DEOXY-D-GLUCITOL
Freeman, Fillmore,Robarge, Kirk D.
, p. 1 - 12 (2007/10/02)
Cyclization of 2,3,5-tri-O-benzyl-1,2-dideoxy-D-arabino-hex-1-enitol (2) with mercuric acetate, mercuric trifluoroacetate, iodine, and N-bromosuccinimide gave preponderantly the allo isomer of the C-arabinofuranosyl structure. 1-Amino-2,5-anhydro-3,4,6-tr
SYNTHESIS OF C-ARABINOFURANOSYL COMPOUNDS. PHOSPHONATE AND CARBOXYLATE ISOESTERS OF D-ARABINOSE 1,5-BISPHOSPHATE
Maryanoff, Bruce E.,Nortey, Samuel O.,Inners, Ruth R.,Campbell, Susan A.,Reitz, Allen B.,Liotta, Dennis
, p. 259 - 278 (2007/10/02)
Electrophile-mediated cyclization of 3,4,6-tri-O-benzyl-1,2-dideoxy-D-arabino-hex-1-enitol with N-bromosuccinimide yielded primarily 2,5-anhydro-3,4,6-tri-O-benzyl-1-bromo-1-deoxy-D-glucitol (10).This apparently kinetically controlled reaction was of key
