1022159-60-9Relevant academic research and scientific papers
α-olefins as alkenylmetal equivalents in catalytic conjugate addition reactions
Ho, Chun-Yu,Ohmiya, Hirohisa,Jamison, Timothy F.
, p. 1893 - 1895 (2008)
(Chemical Equation Presented) In the presence of a silyl triflate and an amine base, a nickel-phosphine complex catalyzes the direct conjugate addition of ethylene, α-olefins, and aryl alkenes to unsaturated aldehydes and ketones. The enolsilane products are isolated in good to very high yield, and in very high stereoselectivity for some cases. The alkene is a functional equivalent of an alkenylmetal reagent in the transformation.
