1023053-17-9

Basic information

• Product Name: N-(3,3-dimethylbutyl)-4-methylbenzenesulfonamide
• Synonyms: N-(3,3-dimethylbutyl)-4-methylbenzenesulfonamide
• CAS NO: 1023053-17-9
• Molecular Weight: 255.381
• Mol File: 1023053-17-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: N-(3,3-dimethylbutyl)-4-methylbenzenesulfonamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-(3,3-dimethylbutyl)-4-methylbenzenesulfonamide(1023053-17-9)
• EPA Substance Registry System: N-(3,3-dimethylbutyl)-4-methylbenzenesulfonamide(1023053-17-9)

Safety Data

• Hazardous Substances Data: 1023053-17-9(Hazardous Substances Data)

Upstream product

• 624-95-3 3,3-dimethylbutanol 
• 70-55-3 toluene-4-sulfonamide 
• 6367-75-5 2-(tosylamino)ethyl p-toluenesulfonate 
• 2259-30-5 tert-butylmagnesium bromide 
• 15673-00-4 3,3-dimethylbutylamine 
• 98-59-9 p-toluenesulfonyl chloride 

Relevant articles and documents

Cu(II) Porphyrin-catalyzed Coupling of Alkyl Tosylates and Grignard Reagents

Copper(II) porphyrin-catalyzed coupling of alkyl tosylates and alkyl Grignard reagents afforded substituted alkanes. The role of the copper(II) porphyrin complex was examined using EPR and in-situ synchrotron-based X-ray absorption fine structure measurements. These studies suggested that neither Cu redox nor substitution via in-situ generated cuprate was involved in catalysis. The results supported a reaction mechanism involving single electron transfer from copper(II) porphyrin to tosylate to facilitate the nucleophilic addition of Grignard reagents.

Simple and versatile catalytic system for N-alkylation of sulfonamides with various alcohols

"Chemical Equation Presented" A simple and versatile catalytic system for N-alkylation of sulfonamides with various alcohols based on a catalytic hydrogen transfer reaction has been developed under a low catalyst loading of [Cp*lrCl2]2 (0.050-1.5 mol %) in the presence of t-BuOK. A variety of N-alkylated sulfonamides were prepared In good to excellent yields. Mechanistic investigations revealed that the key catalytic species in the present system is a sulfonylimido-bridged unsaturated diirldium complex [(Cp*lr)2(μ-NTs)2].