1023305-04-5

Basic information

• Product Name: [1-methoxy-3-(4-methylphenylsulfanyl)buta-1,3-dienyloxy]trimethylsilane
• Synonyms: [1-methoxy-3-(4-methylphenylsulfanyl)buta-1,3-dienyloxy]trimethylsilane
• CAS NO: 1023305-04-5
• Molecular Weight: 294.49
• Mol File: 1023305-04-5.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: [1-methoxy-3-(4-methylphenylsulfanyl)buta-1,3-dienyloxy]trimethylsilane(CAS DataBase Reference)
• NIST Chemistry Reference: [1-methoxy-3-(4-methylphenylsulfanyl)buta-1,3-dienyloxy]trimethylsilane(1023305-04-5)
• EPA Substance Registry System: [1-methoxy-3-(4-methylphenylsulfanyl)buta-1,3-dienyloxy]trimethylsilane(1023305-04-5)

Safety Data

• Hazardous Substances Data: 1023305-04-5(Hazardous Substances Data)

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 1093350-48-1 3-(4-methylphenylsulfanyl)but-2-enoic acid methyl ester 
• 1023304-99-5 C₁₂H₁₄O₂S 

Downstream Products

• 1023305-14-7 methyl 4,6-dimethyl-5-(2-chloroethyl)-2-(4-methylphenylsulfanyl)benzoate 
• 1023305-15-8 methyl 4-methyl-5-(2-chloroethyl)-2-(4-methylphenylsulfanyl)-6-phenylbenzoate 
• 1023305-16-9 methyl 4-methyl-5-(2-bromoethyl)-2-(4-methylphenylsulfanyl)-6-phenylbenzoate 
• 1520854-04-9 methyl 6-(4-methylphenyl)sulfanyl-2,4-dimethyl-3-[2-(4-methylphenyl)diazen-1-yl]benzoate 
• 1520853-96-6 methyl 6-(4-methylphenyl)sulfanyl-2,4-dimethyl-3-(2-phenyldiazen-1-yl)benzoate 
• 1254592-93-2 methyl 2,4-dimethyl-6-[(4-methylphenyl)sulfanyl]-3-(phenylselanyl)benzoate 
• 1229787-48-7 methyl 2-hydroxy-6-(2-methoxy-2-oxoethyl)-4-[(4-methylphenyl)sulfanyl]benzoate 
• 1189373-72-5 dimethyl 3-hydroxy-5-(4-methylphenylsulfanyl)phthalate 
• 1195804-25-1 methyl 4-methyl-2-(methylsulfanyl)-6-(p-tolylsulfanyl)benzoate 
• 1190220-28-0 methyl 4,6-dimethyl-5-(2-bromoethyl)-2-(4-methylphenylsulfanyl)benzoate 
• 1190219-98-7 2,4-dimethyl-6-(4-tolylsulfanyl)benzoic acid methyl ester 
• 1179980-50-7 methyl 4-methoxy-2-methyl-6-(4-methylphenylsulfanyl)benzoate 
• 1179980-57-4 methyl 6-(4-methylphenylsulfanyl)-2-ethyl-4-methoxybenzoate 
• 1140530-63-7 methyl 6-methyl-2-(p-tolylsulfanyl)benzoate 

Relevant articles and documents

Synthesis of Methyl 2-arylthio-5 -aryldiazenylbenzoates by Formal [3+3]Cyclizations of 3-arylthio-1-silyloxy-1,3-butadienes with 2-aryldiazenyl-3-silyloxy-2-en-1-ones

The formal [3+3]cyclization of 3-arylthio-1-silyloxy-1,3-butadienes with 2-aryldiazenyl-3-silyloxy-2-en-1-ones afforded a variety of 2-arylthio-5- aryldiazenylbenzoates.

Synthesis of functionalized 2-(arylthio)benzoates by formal [3+3] cyclizations of 3-arylthio-1-silyloxy-1,3-butadienes with 3-silyloxy-2-en-1-ones and 1,3-diacylcyclopropanes

Functionalized 2-(arylthio)benzoates are prepared by formal [3+3] cyclizations of 3-arylthio-1-trimethylsilyloxy-1,3-butadienes with 3-silyloxy-2-en-1-ones and 1,1-diacylcyclopropanes.

Regioselective synthesis of functionalized 2-(phenylthio)benzoates by '[3+3] cyclization/homo-Michael' reactions of 1-methoxy-1-trimethylsilyloxy-3-phenylthio-1,3-butadienes with 1,1-diacylcyclopropanes

2-(Phenylthio)benzoates containing a remote halide function are regioselectively prepared by '[3+3] cyclization/homo-Michael' reactions of 1-methoxy-1-trimethylsilyloxy-3-phenylthio-1,3-butadienes with 1,1-diacylcyclopropanes.