[1-methoxy-3-(4-methylphenylsulfanyl)buta-1,3-dienyloxy]trimethylsilane

Base Information

• Chemical Name: [1-methoxy-3-(4-methylphenylsulfanyl)buta-1,3-dienyloxy]trimethylsilane
• CAS No.: 1023305-04-5
• Molecular Formula: C₁₅H₂₂O₂SSi
• Molecular Weight: 294.49
• Mol file: 1023305-04-5.mol

Synonyms:[1-methoxy-3-(4-methylphenylsulfanyl)buta-1,3-dienyloxy]trimethylsilane

Chemical Property of [1-methoxy-3-(4-methylphenylsulfanyl)buta-1,3-dienyloxy]trimethylsilane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [1-methoxy-3-(4-methylphenylsulfanyl)buta-1,3-dienyloxy]trimethylsilane

There total 2 articles about [1-methoxy-3-(4-methylphenylsulfanyl)buta-1,3-dienyloxy]trimethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

chloro-trimethyl-silane (75-77-4) + C12H14O2S (1023304-99-5) → [1-methoxy-3-(4-methylphenylsulfanyl)buta-1,3-dienyloxy]trimethylsilane (1023305-04-5)

Guidance literature:

With lithium diisopropyl amide; In tetrahydrofuran; at -78 - 20 ℃;

DOI:10.1016/j.tetlet.2008.02.025

Reference yield: 88.0%

chloro-trimethyl-silane (75-77-4) + 3-(4-methylphenylsulfanyl)but-2-enoic acid methyl ester (1093350-48-1) → [1-methoxy-3-(4-methylphenylsulfanyl)buta-1,3-dienyloxy]trimethylsilane (1023305-04-5)

Guidance literature:

3-(4-methylphenylsulfanyl)but-2-enoic acid methyl ester; With lithium diisopropyl amide; In tetrahydrofuran; at -78 ℃; for 1h;

chloro-trimethyl-silane; In tetrahydrofuran; at -78 - 20 ℃; for 14h;

DOI:10.1055/s-0028-1083516

Reference yield: 83.0%

[1-methoxy-3-(4-methylphenylsulfanyl)buta-1,3-dienyloxy]trimethylsilane (1023305-04-5) + dimethyl penta-2,3-dienedioate (1712-36-3) → methyl 2-hydroxy-6-(2-methoxy-2-oxoethyl)-4-[(4-methylphenyl)sulfanyl]benzoate (1229787-48-7)

Guidance literature:

[1-methoxy-3-(4-methylphenylsulfanyl)buta-1,3-dienyloxy]trimethylsilane; dimethyl penta-2,3-dienedioate; at 50 - 70 ℃; for 12h;

With triethylamine hydrofluoride; In ethanol; at 20 ℃; for 0.166667h; regioselective reaction;

DOI:10.1002/hlca.200900348

upstream raw materials:

chloro-trimethyl-silane

C₁₂H₁₄O₂S

3-(4-methylphenylsulfanyl)but-2-enoic acid methyl ester

Downstream raw materials:

methyl 4,6-dimethyl-5-(2-chloroethyl)-2-(4-methylphenylsulfanyl)benzoate

methyl 4-methyl-5-(2-chloroethyl)-2-(4-methylphenylsulfanyl)-6-phenylbenzoate

methyl 4-methyl-5-(2-bromoethyl)-2-(4-methylphenylsulfanyl)-6-phenylbenzoate

methyl 4'-chloro-3-(p-tolylsulfanyl)biphenyl-2-carboxylate