102339-68-4

Upstream product

• 112790-78-0 (3R,4R)-4-benzyloxy-hexa-1,5-dien-3-ol 
• 100-39-0 benzyl bromide 
• 19700-97-1 3,4-dihydroxy-D,L-threo-hexa-1,5-diene 
• 102235-52-9 4-O-Benzyl-DL-threo-1,5-hexadien-3,4-diol 

Downstream Products

• 928307-02-2 (R)-2-((1S,2R)-1-allyloxy-2-benzyloxy-but-3-enyl)-oxirane 
• 1006596-25-3 2-(1,2-bis(benzyloxy)-but-3-enyl)-oxirane 
• 1219744-57-6 (1S,2R)-2-(benzyloxy)-1-((R)-oxiran-2-yl)but-3-enyl acrylate 
• 102235-53-0 4-O-Benzyl-5,6-didesoxy-1-O-(isopropyl)-D-lyxo-hex-5-enitol 

Relevant academic research and scientific papers

Palladium-catalyzed O-allylation of α-hydroxy carbonyl compounds

α-Hydroxy carbonyl compounds undergo smooth O-allylation using allylic carbonates and Pd(0) catalysts. This method has significant advantages over other O-allylation methods as it provides a solution to several problems previously observed for this synthe

Tandem RCM-isomerization approach to glycals of desoxyheptoses from a common precursor

Ring closing metathesis and tandem RCM-isomerization have been applied to the synthesis of six- to eight-membered oxacycles, starting from a common precursor. The products of the tandem RCM-isomerization sequence are glycals of 3-deoxyheptoses of varying

De novo Synthesis of Carbohydrates and Related Natural Products, 22. - Synthesis of D-Digitoxose from meso-Divinylglycol

Selective monobenzylation of meso- and rac-divinylglycol (2-m and 2-d,l) affords racemates (+/-)-8 and (+/-)-10, respectively; they are transferred with the help of the Sharpless method under kinetic racemate resolution diastereoselectively into the enant