112790-78-0

Upstream product

• 1069-23-4 (3R,4R)-1,5-hexadiene-3,4-diol 
• 100-39-0 benzyl bromide 
• 112699-61-3 C₂₄H₃₀O₁₆S₄ 
• 112723-62-3 Acetic acid (1S,2S,3R)-2-benzyloxy-1-((R)-1,2-bis-methanesulfonyloxy-ethyl)-3,4-bis-methanesulfonyloxy-butyl ester 
• 7462-38-6 O³,O⁴-dibenzoyl-D-mannitol 
• 130282-82-5 D_g-threo-dibenzoyloxy-hexadiene-(1.5) 
• 69-65-8 mannitol 

Downstream Products

• 928307-05-5 (2S,3R,4R)-1,2-epoxy-4-(benzyloxy)-hex-5-en-3-ol 
• 112699-66-8 (E)-(R)-6-Benzyloxy-octa-4,7-dienoic acid ethyl ester 
• 803684-08-4 acrylic acid (2R)-benzyloxy-(1R)-vinylbut-3-enyl ester 
• 928307-02-2 (R)-2-((1S,2R)-1-allyloxy-2-benzyloxy-but-3-enyl)-oxirane 
• 102339-68-4 1,2-Anhydro-4-O-benzyl-5,6-didesoxy-D-lyxo-hex-5-enitol 
• 1005759-10-3 (3R,4R)-3-benzyloxy-4-allyloxyhexa-1,5-diene 
• 1275581-33-3 (3R,4R)-4-(benzyloxy)-hexa-1,5-dien-3-yl methyl carbonate 
• 1275581-42-4 (2S,3S,4R)-methyl 4-(benzyloxy)-2-(prop-2-ynyl)-3-vinylhex-5-enoate 
• 1275581-43-5 (2R,3S,4R)-methyl 4-(benzyloxy)-2-(prop-2-ynyl)-3-vinylhex-5-enoate 
• 1275581-41-3 (3R,4R)-methyl-4-(benzyloxy)-3-vinylhex-5-enoate 
• 1275581-38-8 diethyl 2-((3'S,4'R)-4'-(benzyloxy)hexa-1',5'-dien-3'-yl)malonate 
• 1275581-34-4 (3R,4R)-4-(benzyloxy)-hexa-1,5-dien-3-yl ethyl carbonate 
• 1275581-35-5 (3R,4R)-4-(benzyloxy)hexa-1,5-dien-3-yl tert-butyl carbonate 
• 1200-22-2 (R)-1,2-dithiolane-3-pentanoic acid 

Relevant academic research and scientific papers

Bidirectional Synthesis of 6-Acetoxy-5-hexadecanolide, the Mosquito Oviposition Pheromone of Culex quinquefasciatus, from a C2-Symmetric Building Block Using Olefin Metathesis Reactions

(5R,6S)-6-Acetoxy-5-hexadecanolide (MOP) is the oviposition pheromone of the mosquito Cx. quinquefasciatus, a vector of pathogens causing a variety of tropical diseases. We describe and evaluate herein three syntheses of MOP starting from mannitol-derived

Convergent total synthesis of squamostolide

A convergent total synthesis of the Annonaceous acetogenin squamostolide, in a longest linear sequence of nine steps from d-mannitol, is reported. Central to the efficiency of the synthesis is a highly selective tandem ring-closing/cross metathesis step in which lactone formation and fragment coupling are accomplished.

Concise total synthesis of (-)-muricatacin by tandem ring-closing/cross metathesis

(Chemical Equation Presented) A strategy for the synthesis of chiral 5-(1-hydroxyalk-2-enyl)-5H-furan-2-ones and its application to the total synthesis of (-)-muricatacin, in four steps and 37% overall yield from (R,R)-hexa-1,5-diene-3,4-diol, are describ

SYNTHESIS OF (3R,4R)-1,5-HEXADIEN-3,4,-DIOL AND ITS UNSYMMETRICAL DERIVATIVES : APPLICATION TO (R)-(+)-α-LIPOIC ACID

(3R,4R)-1,5-Hexadien-3,4-diol and its umsymmetrical derivatives were prepared starting from D-mannitol and their utility in the synthesis of (R)-(+)-α-lipoic acid has been explored.