102364-17-0

Upstream product

• 26114-12-5 2-(4-propylphenyl)acetic acid 
• 3585-46-4 Diethyl-(4-propylphenyl)malonat 

Downstream Products

• 81221-33-2 4-[5-(4-Propyl-phenyl)-[1,3]dioxan-2-yl]-benzonitrile 
• 81221-33-2 4-[5-(4-Propyl-phenyl)-[1,3]dioxan-2-yl]-benzonitrile 
• 126747-08-8 2-(4-cyanophenyl)-5-(4-propylphenyl)-1,3,2-dioxaborinane 
• 126781-46-2 2-(4-methoxyphenyl)-5-(4-propylphenyl)-1,3,2-dioxaborinane 
• 124651-80-5 <4-Fluorphenyl>- 
• 124651-81-6 <4-Fluorphenyl>- 
• 124652-03-5 Diethyl-<3-(4-propylphenyl)-1,1-cyclobutandicarboxylat> 
• 124651-99-6 3-(4-Propyl-phenyl)-cyclobutanecarboxylic acid 
• 124652-02-4 <2-(4-Propylphenyl)-1,3-propandiyl>bis(4-toluolsulfonat) 

Relevant academic research and scientific papers

Synthesis and physical properties of novel liquid crystals containing 2,3-difluorophenyl and 1,3-dioxane units

Three series of liquid crystalline materials have been synthesized: 2-(2,3-difluoro-4-alkoxyphenyl)-5-(4-alkylphenyl)-1,3-dioxanes (m,On-DFPPD), 2-(2,3-Difluoro-4-alkoxyphenyl)-5-(2-fluoro-4-alkylphenyl)-1,3-dioxanes (m,On-DFPFPD) and 2-(2,3-Difluoro-4-al

Synthesis of Stereoisomeric 3-Substituted Cyclobutanecarboxylic Acid Derivatives

The preparation of 3-substituted cyclobutanecarboxylic acids by ring forming malonic ester cycloalkylation/saponification/decarboxylation leads to 50:50 cis/trans mixtures.Only some polar ester derivatives 2 can be separated by chromatographic methods.Catalytic hydrogenation of 3-substituted cyclobutanecarboxylic acids 3, however, gives the cis acids 4 with 90-95 percent selectivity.Reduction of the same acids 3 by Zn in aqueous HCl/THF leads to the trans acids 6 with 90-93 percent selectivity.