102389-99-1Relevant academic research and scientific papers
Enantioselective synthesis of (+)-petromyroxol, enabled by rhodium-catalyzed denitrogenation and rearrangement of a 1-sulfonyl-1,2,3-triazole
Boyer, Alistair
, p. 4771 - 4775 (2015)
Petromyroxol is a nonracemic mixture of enantiomeric oxylipids isolated from water conditioned with larval sea lamprey. The (+)-antipode exhibits interesting biological properties, but only 1 mg was isolated from >100000 L of water. Recently, transition-m
Synthesis of the rarely obtained syn-Adducts in the Reaction of Organocopper Compounds with 2,3-O-Isopropylideneglyceraldehyde. Preparation of Optically Active Epoxy Alcohols
Sato, Fumie,Kobayashi, Yuichi,Takahashi, Osamu,Chiba, Tsunehisa,Takeda, Yoshiyuki,Kusakabe, Masato
, p. 1636 - 1638 (2007/10/02)
Organocopper compounds, prepared from Grignard reagents and copper(I) iodide in tetrahydrofuran-dimethyl sulphide, react with 2,3-O-isopropylideneglyceraldehyde highly stereoselectively (>10:1) affording the rarely obtained syn-addition products which can be readily converted into optically active epoxy alcohols, useful intermediates in organic synthesis.
