102402-80-2 Usage
General Description
1-Trimethylstannyl-3,3-dimethoxypropane, also known as Bis(trimethyltin) acetal or TMSTMA, is a chemical compound with the molecular formula C9H22O2Sn. It is a colorless, flammable liquid that is commonly used as a reagent in organic synthesis. TMSTMA is a versatile building block in organic chemistry, often used in cyclopropanation and nucleophilic addition reactions. It is also employed in the preparation of various compounds, including pharmaceutical intermediates and agrochemicals. TMSTMA is known for its high reactivity and selectivity, making it a valuable tool in the field of organic chemistry. However, it is important to handle this compound with caution as it is toxic and can pose environmental risks if not properly managed.
Check Digit Verification of cas no
The CAS Registry Mumber 102402-80-2 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,0,2,4,0 and 2 respectively; the second part has 2 digits, 8 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 102402-80:
(8*1)+(7*0)+(6*2)+(5*4)+(4*0)+(3*2)+(2*8)+(1*0)=62
62 % 10 = 2
So 102402-80-2 is a valid CAS Registry Number.
102402-80-2Relevant articles and documents
NOVEL ANNULATION REACTIONS : THE DIRECT SYNTHESIS OF CYCLOPENTANES USING A LEWIS ACID ACTIVATED BISFUNCTIONAL ANNULATING REAGENT
Lee, Thomas V.,Richardson, Kevan A.
, p. 3629 - 3632 (1985)
In a novel one-pot reaction 3,3-Dimethoxy-1-trimethylstannyl-propane (1) reacts in the presence of Lewis acids with O-silylated enolates in a annulation to form fused cyclopentanes possessing a bridgehead hydroxy group.