NOVEL ANNULATION REACTIONS : THE DIRECT SYNTHESIS OF CYCLOPENTANES USING A LEWIS ACID ACTIVATED BISFUNCTIONAL ANNULATING REAGENT

DOI: 10.1016/S0040-4039(00)89209-6

Source and publish data:

Tetrahedron Letters p. 3629 - 3632 (1985)

Update date:2022-07-29

Topics:

Authors:

Lee, Thomas V.

Richardson, Kevan A.

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Article abstract of DOI:10.1016/S0040-4039(00)89209-6

In a novel one-pot reaction 3,3-Dimethoxy-1-trimethylstannyl-propane (1) reacts in the presence of Lewis acids with O-silylated enolates in a <3+2> annulation to form fused cyclopentanes possessing a bridgehead hydroxy group.

Full text of DOI:10.1016/S0040-4039(00)89209-6

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