102438-33-5Relevant academic research and scientific papers
Dealkenylative Thiylation of C(sp3)-C(sp2) Bonds
Smaligo, Andrew J.,Kwon, Ohyun
supporting information, p. 8592 - 8597 (2019/10/14)
Carbon-carbon bond fragmentations are useful methods for the functionalization of molecules. The value of such cleavage events is maximized when paired with subsequent bond formation. Herein we report a protocol for the cleavage of an alkene C(sp3)-C(sp2) bond, followed by the formation of a new C(sp3)-S bond. This reaction is performed in nonanhydrous solvent and open to the air, employs common starting materials, and can be used to rapidly diversify natural products.
The Stereochemistry of Organometallic Compounds. XXXIX. Hydroformylation of Alkenes Containing Sulfur and Oxygen Substituents: a Potential Route to 1,4-Dialdehydes
Campi, Eva M.,Jackson, W. Roy,Perlmutter, Patrick,Tasdelen, E. Elizabeth
, p. 995 - 1007 (2007/10/02)
Rhodium-catalysed hydroformylation of a series of unsaturated thioethers, dithians, dioxans and dioxolans has been shown to give aldehydes in very good yield.The regioselectivity in some cases appears to be influenced by coordination between the rhodium c
Synthese de lactones a cycle moyen: Application a la synthese du pentadecanolide-15 et du phoracantholide I
Cossy, Janine,Pete, Jean-Pierre
, p. 989 - 994 (2007/10/02)
Medium ring size lactones can be prepared from bifunctional commercial starting compounds in high yields, using a few step sequence.Lactonisation is obtained by cyclization of the free ω-hydroxyacids or by the cyclization of ω-hydroxyacids having the hydroxy and carboxy group protected.
Carbenoid Anion Behavior of Dilithio Derivatives of Thioacetal Alcohols. Stereochemistry and Mechanism of Ring Closures by Oxyanion-Facilitated CH Bond Insertion
Ritter, Robert H.,Cohen, Theodore
, p. 3718 - 3725 (2007/10/02)
Like other lithio derivatives of thioacetals bearing a second anionic site, dilithio derivatives of 3,3-, 5,5-, and 6,6-bis(phenylthio) alcohols decompose at or below ambient temperature to yield products ascribable to carbenoid intermediates.The 5,5-deri
