102468-81-5

Upstream product

• 532-31-0 silver benzoate 
• 10368-43-1 (±)-trans-2-bromo-1,2-diphenylethan-1-ol 
• 98-88-4 benzoyl chloride 
• 588-59-0 stilbene 
• 65-85-0 benzoic acid 

Downstream Products

• 38036-63-4 meso-α.α'-dibenzoyloxy-bibenzyl 
• 59517-11-2 (+/-)-1-benzoyloxy-2-hydroxydibenzyl 
• 655-48-1 DL-1,2-diphenylethane-1,2-diol 

Relevant academic research and scientific papers

Nitroxyl Catalysts for Six-Membered Ring Bromolactonization and Intermolecular Bromoesterification of Alkenes with Carboxylic Acids

We developed a nitroxyl-catalyzed bromoesterification of alkenes with bromo reagents, which includes a six-membered ring bromolactonization of alkenyl carboxylic acids catalyzed by AZADO as the nitroxyl radical catalyst, and an intermolecular bromoesterification of alkenes with carboxylic acids using NMO as the N-oxide catalyst. We also accomplished a remote diastereoselective bromohydroxylation via an AZADO-catalyzed six-membered ring bromolactonization and a subsequent ring cleavage reaction with alkylamines to furnish ?-bromo-δ-hydroxy amides with high diastereoselectivity.