102518-70-7

Upstream product

• 102487-59-2 Methanesulfonic acid (2R,3R)-3-[(4S,5S)-5-(benzyloxycarbonylamino-methyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-2,3-dihydroxy-propyl ester 
• 7115-22-2 1-O-benzoyl-2,3:5,6-di-O-isopropylidene-D-mannitol 
• 35023-80-4 2,3:5,6-di-O-isopropylidene-D-mannose oxime 
• 98362-05-1 (R)-((4S,5R)-5-Aminomethyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-methanol 
• 98362-00-6 Methanesulfonic acid (R)-[(4R,5R)-5-(benzyloxycarbonylamino-methyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-methyl ester 
• 98361-99-0 {(4R,5S)-5-[(R)-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-hydroxy-methyl]-2,2-dimethyl-[1,3]dioxolan-4-ylmethyl}-carbamic acid benzyl ester 
• 102487-55-8 (4S,5R)-5-[(R)-(tert-Butyl-dimethyl-silanyloxy)-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-methyl]-2,2-dimethyl-[1,3]dioxolane-4-carbaldehyde oxime 
• 102487-58-1 [(4S,5S)-2,2-Dimethyl-5-((1R,2R)-1,2,3-trihydroxy-propyl)-[1,3]dioxolan-4-ylmethyl]-carbamic acid benzyl ester 
• 102487-54-7 2,3:5,6-Di-O-isopropylidene-4-O-(tert-butyldimethylsilyl)-aldehydo-D-glucose 
• 3969-61-7 2,3,5,6-di-isopropyIidene-1,4-dihydroxy-D-mannitol 
• 102487-60-5 [(4S,5S)-5-((R)-Hydroxy-(R)-oxiranyl-methyl)-2,2-dimethyl-[1,3]dioxolan-4-ylmethyl]-carbamic acid benzyl ester 
• 102487-53-6 4-O-(tert-butyldimethylsilyl)-2,3:5,6-di-O-isopropylidene-aldehydo-D-mannose 
• 102487-52-5 {(4R,5R)-5-[(R)-(tert-Butyl-dimethyl-silanyloxy)-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-methyl]-2,2-dimethyl-[1,3]dioxolan-4-yl}-methanol 
• 102487-56-9 {(4S,5R)-5-[(R)-(tert-Butyl-dimethyl-silanyloxy)-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-methyl]-2,2-dimethyl-[1,3]dioxolan-4-ylmethyl}-carbamic acid benzyl ester 

Downstream Products

• 102487-61-6 [(4S,5R)-5-((2S,3R)-3-Formyl-oxiranyl)-2,2-dimethyl-[1,3]dioxolan-4-ylmethyl]-carbamic acid benzyl ester 
• 72741-87-8 swainsonine 
• 85624-09-5 (3aR,9R,9aR,9bS)-octahydro-2,2-dimethyl-[1,3]dioxolo[4,5-a]indolizin-9-ol 
• 98393-47-6 (E)-3-{(2R,3S)-3-[(4R,5R)-5-(Benzyloxycarbonylamino-methyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-oxiranyl}-acrylic acid ethyl ester 
• 98362-02-8 3-{(2R,3S)-3-[(4R,5R)-5-(Benzyloxycarbonylamino-methyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-oxiranyl}-propionic acid ethyl ester 
• 105878-90-8 (1R,5S,6R,1'S)-7-benzyloxycarbonyl-6-1',2'-dihydroxyethyl-3,3-dimethyl-2,4-dioxa-7-azabicyclo<3.3.0>octane 
• 105929-20-2 (1R,5S,6R)-7-benzyloxycarbonyl-3,3-dimethyl-6-hydroxymethyl-2,4-dioxa-7-azabicyclo<3.3.0>octane 
• 105888-78-6 (3aS,4S,6aR)-4-Formyl-2,2-dimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyrrole-5-carboxylic acid benzyl ester 
• 100937-51-7 (2R,3S,4R)-2-(hydroxymethyl)pyrrolidine-3,4-diol 
• 95189-02-9 1,4-dideoxy-1,4-imino-D-mannitol 
• 98393-46-5 [(4R,5R)-5-((2R,3S)-3-Formyl-oxiranyl)-2,2-dimethyl-[1,3]dioxolan-4-ylmethyl]-carbamic acid benzyl ester 
• 102487-65-0 (S)-3-{(2S,3R)-3-[(4R,5S)-5-(Benzyloxycarbonylamino-methyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-oxiranyl}-3-hydroxy-propionic acid tert-butyl ester 
• 102487-62-7 (R)-3-{(2S,3R)-3-[(4R,5S)-5-(Benzyloxycarbonylamino-methyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-oxiranyl}-3-hydroxy-propionic acid tert-butyl ester 
• 102487-62-7 3-{(2S,3R)-3-[(4R,5S)-5-(Benzyloxycarbonylamino-methyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-oxiranyl}-3-hydroxy-propionic acid tert-butyl ester 

Relevant academic research and scientific papers

TOTAL SYNTHESIS OF (+)-CASTANOSPERMINE FROM D-MANNOSE

A total synthesis of (+)-castanospermine (2) has been achieved starting from D-mannose by a route adopting a double-cyclization process (5c-6) as the key step.

Enantiospecific Total Synthesis of (-)-Swainsonine: New Aplications of Sodium Borohydride Reduction

A short, enantiospecific synthesis of (-)-swainsonine (1) from D-mannose has been achieved by a route involving, as a key step, a double cyclization of 4c.The synthesis takes adventage of new features of sodium borohydride for reducing conjugated esters and lactams.