10256-07-2Relevant academic research and scientific papers
Diastereodivergent Synthesis of Bromoiminolactones: Electrochemical and Chemical Bromoiminolactonization of α-Allylmalonamides
Ishimaru, Keiko,Kuriyama, Masami,Minato, Daishirou,Mizuta, Satoshi,Onomura, Osamu,Yamamoto, Kosuke
supporting information, p. 1204 - 1208 (2019/06/08)
A diastereodivergent synthesis of N-substituted iminolactones by bromoiminolactonization of α-substituted α-allylmalonamides is reported. Whereas bromocyclization under conventional chemical conditions provided cis -bromoiminolactones, electrochemical con
Malonates in cyclocondensation reactions
Stadlbauer, Wolfgang,Badawey, El-Sayed,Hojas, Gerhard,Roschger, Peter,Kappe, Thomas
, p. 338 - 352 (2007/10/03)
The use of malonates such as diethyl malonates 9, (chlorocarbonyl)ketenes 15 and bis(2,4,6-trichlorophenyl) malonates 18 as reagents for cyclocondensation with 1,3-dinucleophiles to give six-membered heterocycles is described. Further attempts to use malonates such as bis(trimethylsilyl) malonates 19 and bis(carbamimidoyl) malonates 29 as new cyclocondensation agents are described.
