10258-67-0

Basic information

• Product Name: (dimethoxythiophosphinoylmercapto)benzene
• Synonyms: (dimethoxythiophosphinoylmercapto)benzene
• CAS NO: 10258-67-0
• Molecular Weight: 234.28
• Mol File: 10258-67-0.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: (dimethoxythiophosphinoylmercapto)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: (dimethoxythiophosphinoylmercapto)benzene(10258-67-0)
• EPA Substance Registry System: (dimethoxythiophosphinoylmercapto)benzene(10258-67-0)

Safety Data

• Hazardous Substances Data: 10258-67-0(Hazardous Substances Data)

Upstream product

• 14684-25-4 Dichlor(phenylthio)phosphan 
• 108-98-5 thiophenol 
• 931-59-9 benzenesulfenyl chloride 
• 369-57-3 benzenediazonium tetrafluoroborate 
• 16001-68-6 potassium O,O-dimethyldithiophosphate 
• 111-34-2 -butyl vinyl ether 
• 4237-00-7 thiophosphoric acid O,O'-dimethyl ester S-phenyl ester 
• 22946-71-0 Thiophosphorous acid O,O'-dimethyl ester S-phenyl ester 
• 100-34-5 benzene diazonium chloride 

Relevant articles and documents

Reactions of arenediazonium tetrafluoroborates with inorganic and organic salts

Arenediazonium tetrafluoroborates were reacted with inorganic and organic salts under anionarylation reaction conditions in the presence of strong nucleophiles (O,O-dimetyl dithiophosphate, N,N-diethyldithiocarbamate, and O-alkyl dithiocarbonate anions) and in the absence of catalysts [Cu(I) and Fe(II) salts] to obtain in high yields (dimethoxythiophosphinoylmercapto)-, (N,N-diethylthiocarbamoylmercapto)-, and (alkoxythiocarbonylmercapto)benzenes. The products of the reactions of arenediazonium tetrafluoroborates with potassium thiocyanate were identified and their compositions were determined. These reactions are proposed to occur by a radical mechanism, both under catalytic and noncatalytic conditions.

Dimethylphosphinothioylthioarylation of Vinyl Butyl Ether

On the basis of anionarylation reaction a method for preparing dithiophosphoric acid derivatives, 1-butoxy-2-arylethyl O,O-dimethyl phosphorodithioates was developed. The reaction of aryldiazonium tetra-fluoroborates with vinyl butyl ether in the presence of O,O-dimethyl phosphorodithioate anion is a new example of a noncatalyzed reaction of diazonium salts with alkenes in the presence of foreign nucleophiles. A mechanism of such reactions is proposed.