102613-04-7

Basic information

• Product Name: N-methoxy-N-methylundec-10-enamide
• CAS NO: 102613-04-7
• Molecular Formula: C₁₃H₂₅NO₂
• Molecular Weight: 227.3431
• Mol File: 102613-04-7.mol
• Article Data: 12

Chemical Properties

• Boiling Point: 294.6°C at 760 mmHg
• Flash Point: 132°C
• Density: 0.913g/cm³
• Vapor Pressure: 0.0016mmHg at 25°C
• Refractive Index: 1.454
• CAS DataBase Reference: N-methoxy-N-methylundec-10-enamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-methoxy-N-methylundec-10-enamide(102613-04-7)
• EPA Substance Registry System: N-methoxy-N-methylundec-10-enamide(102613-04-7)

Safety Data

• Hazardous Substances Data: 102613-04-7(Hazardous Substances Data)

Upstream product

• 38460-95-6 undec-10-enoyl chloride 
• 6638-79-5 N,O-dimethylhydroxylamine*hydrochloride 
• 112-38-9 10-undecenoic acid 

Downstream Products

• 173591-82-7 5-Hydroxy-4-(4-(1-oxoundec-10-en-1-yl)phenyl)-2(5H)-furanone 
• 10403-00-6 (R)-3-methyl-1-cyclopentadecanone 
• 7028-27-5 1-phenylundec-10-en-1-one 
• 5009-33-6 1-dodecen-11-one 
• 75853-49-5 12-methyltridecan-1-al 
• 16899-08-4 10-hydroxytetradecanoic acid 
• 675-95-6 10-oxotetradecanoic acid 

Relevant articles and documents

An iron-catalyzed hydroalkylation reaction of α,β-unsaturated ketones with ethers

A general strategy for the hydroalkylation of vinyl ketones using ethers catalyzed by an iron catalyst is described. This catalytic method permits direct transformation of easily accessible and abundant precursors into highly substituted, structurally diverse and functionally concentrated products.

Continuous photochemical generation of catalytically active [CpRu] + complexes from CpRu(η6-C6H6)PF6

Inter- and intramolecular ene-yne coupling reactions catalyzed by a species generated in situ via photolysis of CpRu(η6-C6H 6)PF6;an inexpensive, readily available, and shelf-stable complex;have been demonstrated under conditions of continuous flow. Importantly, the catalyst can be recovered quantitatively at the end of the reaction. Various functional groups are tolerated by the reaction, which affords skipped diene products in high yields.

Methyl Radical Initiated Kharasch and Related Reactions

An improved procedure to run halogen atom and related chalcogen group transfer radical additions is reported. The procedure relies on the thermal decomposition of di-tert-butylhyponitrite (DTBHN), a safer alternative to the explosive diacetyl peroxide, to produce highly reactive methyl radicals that can initiate the chain process. This mode of initiation generates byproducts that are either gaseous (N2) or volatile (acetone and methyl halide) thereby facilitating greatly product purification by either flash column chromatography or distillation. In addition, remarkably simple and mild reaction conditions (refluxing EtOAc during 30 minutes under normal atmosphere) and a low excess of the radical precursor reagent (2 equivalents) make this protocol particularly attractive for preparative synthetic applications. This initiation procedure has been demonstrated with a broad scope since it works efficiently to add a range of electrophilic radicals generated from iodides, bromides, selenides and xanthates over a range of unactivated terminal alkenes. A diverse set of radical trap substrates exemplifies a broad functional group tolerance. Finally, di-tert-butyl peroxyoxalate (DTBPO) is also demonstrated as alternative source of tert-butoxyl radicals to initiate these reactions under identical conditions which gives gaseous by-products (CO2). (Figure presented.).

Broadly Applicable Ytterbium-Catalyzed Esterification, Hydrolysis, and Amidation of Imides

An efficient, broadly applicable, operationally simple, and divergent process for the transformation of imides into a range of carboxylic acid derivatives under mild conditions is reported. By simply using catalytic amounts of ytterbium(III) triflate as a Lewis acid promoter in the presence of alcohols, water, amines, or N,O-dimethylhydroxylamine, a broad range of imides is smoothly and readily converted to the corresponding esters, carboxylic acids, amides, and Weinreb amides in good yields. This method notably enables an easy cleavage of oxazolidinone-based auxiliaries.