N-Methoxy-N-methyl-10-undecenamide

Base Information

• Chemical Name: N-Methoxy-N-methyl-10-undecenamide
• CAS No.: 102613-04-7
• Molecular Formula: C13H25 N O2
• Molecular Weight: 227.347
• NSC Number: 162234
• DSSTox Substance ID: DTXSID50907939
• Nikkaji Number: J96.584G
• Wikidata: Q82877257
• Mol file: 102613-04-7.mol

Synonyms:N-Methoxy-N-methyl-10-undecenamide;n-methoxy-n-methylundec-10-enamide;102613-04-7;10-Undecenamide, N-methoxy-N-methyl-;BRN 3603945;NSC162234;SCHEMBL9260765;DTXSID50907939;NLZGKSBDHFLMTQ-UHFFFAOYSA-N;NSC-162234

Chemical Property of N-Methoxy-N-methyl-10-undecenamide

Chemical Property:

• Vapor Pressure: 0.0016mmHg at 25°C
• Boiling Point: 294.6°Cat760mmHg
• Flash Point: 132°C
• Density: 0.913g/cm³
• XLogP3: 3.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 10
• Exact Mass: 227.188529040
• Heavy Atom Count: 16
• Complexity: 192

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CN(C(=O)CCCCCCCCC=C)OC

Technology Process of N-Methoxy-N-methyl-10-undecenamide

There total 6 articles about N-Methoxy-N-methyl-10-undecenamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.8%

undec-10-enoyl chloride (38460-95-6) + Ν,Ο-dimethylhydroxylamine hydrochloride → N-methyl-N-methoxyundec-10-enamide (102613-04-7)

Guidance literature:

In dichloromethane; at 5 - 10 ℃; Temperature;

Reference yield: 95.0%

10-undecenoic acid (112-38-9) + N,O-dimethylhydroxylamine*hydrochloride (6638-79-5) → N-methyl-N-methoxyundec-10-enamide (102613-04-7)

Guidance literature:

With 1,1'-carbonyldiimidazole; In dichloromethane;

DOI:10.1002/anie.200802106

Reference yield: 91.0%

undec-10-enoyl chloride (38460-95-6) + N,O-dimethylhydroxylamine*hydrochloride (6638-79-5) → N-methyl-N-methoxyundec-10-enamide (102613-04-7)

Guidance literature:

With N-ethyl-N,N-diisopropylamine; In dichloromethane; at 0 - 20 ℃; for 6h;

DOI:10.1002/cjoc.201400862

upstream raw materials:

10-undecenoic acid

N,O-dimethylhydroxylamine*hydrochloride

undec-10-enoyl chloride

Downstream raw materials:

5-Hydroxy-4-(4-(1-oxoundec-10-en-1-yl)phenyl)-2(5H)-furanone

(R)-3-methyl-1-cyclopentadecanone

1-phenylundec-10-en-1-one

1-dodecen-11-one

Refernces

• 1、 Shen, Junwei,Shi, Yong,Tian, Weisheng. "Synthesis of (R)-(-)-muscone from (R)-5-bromo-4-methylpentanoate: A chiron approach". . p. 683 - 687. Retrieved 2015.
• 2、 Bergamaschi, Enrico,Chen, Yi-Kai,Hohenadel, Melissa,Lunic, Danijela,McLean, Liam A.,Teskey, Christopher J.. "Controlling Chemoselectivity of Catalytic Hydroboration with Light". supporting information. . Retrieved 2022/01/13.
• 3、 Sui, Guoqing,Lv, Qingyun,Song, Xiaoqing,Guo, Huihui,Dai, Jiatong,Ren, Li,Lee, Chi-Sing,Zhou, Wenming,Hao, Hong-Dong. "Chemoselective reduction of aldehydes: Via a combination of NaBH4 and acetylacetone". supporting information. p. 15793 - 15796. Retrieved 2019/10/19.