102614-92-6

Basic information

• Product Name: (dl)-3-methyl-1-phenylheptane
• CAS NO: 102614-92-6
• Molecular Weight: 190.329
• Mol File: 102614-92-6.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: (dl)-3-methyl-1-phenylheptane(CAS DataBase Reference)
• NIST Chemistry Reference: (dl)-3-methyl-1-phenylheptane(102614-92-6)
• EPA Substance Registry System: (dl)-3-methyl-1-phenylheptane(102614-92-6)

Safety Data

• Hazardous Substances Data: 102614-92-6(Hazardous Substances Data)

Upstream product

• 2344-70-9 1-phenyl-3-butanol 
• 107943-05-5 3-methyl-1-phenylheptan-3-ol 
• 59456-20-1 (rac)-(3-iodobutyl)benzeze 
• 693-04-9 butyl magnesium bromide 
• 693-02-7 hex-1-yne 
• 536-74-3 phenylacetylene 
• 3277-89-2 phenethylmagnesium bromide 
• 591-78-6 n-hexan-2-one 
• 100-42-5 styrene 
• 37509-99-2 di-n-hexylmagnesium 

Relevant articles and documents

Nickel-catalyzed alkyl-alkyl cross-coupling reactions of non-activated secondary alkyl bromides with aldehydes as alkyl carbanion equivalents

A novel nickel-catalyzed alkyl-alkyl cross coupling of non-activated secondary alkyl bromides with aldehydes via hydrazone intermediates has been developed. Aldehydes as alkyl carbanion equivalents replace traditional organometallic reagents. This coupling occurs on the carbon of the hydrazone rather than the nitrogen. In addition, non-activated primary and tertiary alkyl bromides also undergo the cross-coupling reaction to form new C(sp3)-C(sp3) bonds in moderate yields.

B(C6F5)3-Catalyzed Hydrodesulfurization Using Hydrosilanes - Metal-Free Reduction of Sulfides

B(C6F5)3-catalyzed hydrodesulfurization of carbon-sulfur bonds was achieved using triethylsilane as the reducing agent. The corresponding products were obtained in good yields under mild reaction conditions. This protocol could be applied to the reduction of sulfides, including benzyl and alkyl sulfides and dithianes, with high chemoselectivities. (Chemical Equation Presented).

CATYLYTIC SYNTHESIS AND REACTIONS OF MAGNESIOCYCLOALKANES. 2. SYNTHESIS OF SUBSTITUTED MAGNESIOCYCLOPENTANES IN THE PRESENCE OF ZYRCONIUM COMPLEXES

Catalytic cyclometallation of styrene, m-methylstyrene, p-tert-butylstyrene, and 1-hexene with di n-alkylmagnesium compounds (n-R2Mg, where R=C3H7, C4H9, C6H13) in the presence of Cp2Zr2Cl2 has been given high yields of 2,4-disubstituted magnesiocyclopentanes.The probable mode of formation of magnesiocyclopentanes, involving zirconocyclopentanes formed from Cp2ZrCl2, n-R2Mg, and the appropiate olefins as reactive intermediates in the cyclometallation, is discussed. Keywords: catalytic synthesis, substituted styrenes, alkenes, magnesium alkyls.