1026471-76-0

Basic information

• Product Name: (phenyl)[2,4,5-tris(trimethylsilyl)phenyl]iodonium triflate
• Synonyms: (phenyl)[2,4,5-tris(trimethylsilyl)phenyl]iodonium triflate
• CAS NO: 1026471-76-0
• Molecular Weight: 646.732
• Mol File: 1026471-76-0.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (phenyl)[2,4,5-tris(trimethylsilyl)phenyl]iodonium triflate(CAS DataBase Reference)
• NIST Chemistry Reference: (phenyl)[2,4,5-tris(trimethylsilyl)phenyl]iodonium triflate(1026471-76-0)
• EPA Substance Registry System: (phenyl)[2,4,5-tris(trimethylsilyl)phenyl]iodonium triflate(1026471-76-0)

Safety Data

• Hazardous Substances Data: 1026471-76-0(Hazardous Substances Data)

Upstream product

• 1493-13-6 trifluorormethanesulfonic acid 
• 3240-34-4 [bis(acetoxy)iodo]benzene 
• 17156-61-5 1,2,4,5-tetrakis(trimethylsilyl)benzene 
• 536-80-1 iodosylbenzene 
• 2926-30-9 sodium triflate 
• 95-94-3 1,2,4,5-tetrachlorobenzene 

Downstream Products

• 220300-22-1 6,7-Bis-trimethylsilanyl-1,4-dihydro-1,4-epiazano-naphthalene-9-carboxylic acid benzyl ester 
• 220300-25-4 C₃₀H₃₇NO₆Si₂ 
• 1633750-77-2 1,5,6,7,8-pentaphenyl-1H-naphtho[2,3-d]triazole 
• 1633750-72-7 (phenyl)(3-trimethylsilyl-5,6,7,8-tetraphenyl-2-naphthalen-yl)iodonium triflate 
• 1633750-74-9 1,4-dihydro-5,6,7,8-tetraphenyl-1,4-epoxyanthracene 

Relevant articles and documents

5,6-Bis(trimethylsilyl)benzo[c]furan: An isolable versatile building block for linear polycyclic aromatic compounds

Benzo[c]furans are a class of interesting and highly reactive compounds that readily undergo Diels-Alder cycloaddition with dienophiles to restore their aromaticity. Initially, the s-tetrazine approach established by Warrener was chosen for the synthesis of the title molecule. However, it was discovered that the rate of production of isobenzofuran from this approach was too slow to react with the fugitive arynes. Consequently, an alternative route was employed to realize the title molecule in a neat state. In this way, the reactions between the title molecule and arynes were successfully achieved. Herein, two synthetic approaches towards the title molecule and its further manipulation for the preparation of silylated linear polycyclic aromatic hydrocarbons (PAH) were reported.

A mild and efficient method for the synthesis of mixed adducts of 1,4-bis-benzyne

Unsymmetrical adducts of 1,4-bis-benzyne ? have been prepared by the addition of dienes to mohobenzynes generated sequentially from 1,2,4,5-tetrakis(trimethylsilyl)benzene.