1026561-05-6

Basic information

• Product Name: 1-[1-Ethoxy-1-(1-phenyl-1-trimethylsilanyloxy-ethyl)-allyl]-1H-benzotriazole
• CAS NO: 1026561-05-6
• Molecular Weight: 395.577
• Mol File: 1026561-05-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-[1-Ethoxy-1-(1-phenyl-1-trimethylsilanyloxy-ethyl)-allyl]-1H-benzotriazole(CAS DataBase Reference)
• NIST Chemistry Reference: 1-[1-Ethoxy-1-(1-phenyl-1-trimethylsilanyloxy-ethyl)-allyl]-1H-benzotriazole(1026561-05-6)
• EPA Substance Registry System: 1-[1-Ethoxy-1-(1-phenyl-1-trimethylsilanyloxy-ethyl)-allyl]-1H-benzotriazole(1026561-05-6)

Safety Data

• Hazardous Substances Data: 1026561-05-6(Hazardous Substances Data)

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 172846-87-6 3-(Benzotriazol-1-yl)-3-ethoxy-2-phenylpent-4-en-2-ol 
• 161607-20-1 3-(benzotriazol-1-yl)-3-ethoxy-1-propene 
• 98-86-2 acetophenone 

Downstream Products

• 68487-07-0 1-Hydroxy-1-methyl-1-phenylpentan-2-one 

Relevant articles and documents

Novel Routes to Enol Ethers, Unsymmetrical Ketones, α-Bromoalkyl Ketones, 1,4-Diketones, 2-Ethoxy-2-cyclopenetenones, and α-Keto Enamines

Highly regioselectve SN2' reactions of adducts 6 (readily prepared by reactions of halides with the allyl anion 12 of 11) with Grignard reagents gave enol ethers 13, which were converted (in one-pot reactions from 11) into ketones 14 and α-bromoalkyl ketones 15 in good yields.The monoprotected 1,4-diketone derivative 16 (prepared by Michael addition of the allyl anion 12 with methyl vinyl ketone) was converted both into 1,4-diketones 18 and into protected γ-hydroxyalkyl ketone 20 by propenoyl, or to both functionalities.The allyl anion 12 with α-substituted acetic esters gave α-acylated adducts 24, which underwent in situ unfavored endo-trig cyclization upon treatment with NaH and secondary amines, to give 2-ethoxy-2-cyclopenetenones 27 and 28 and α-keto enamines 25 in good yield.The mechanism for the cyclization is discussed.