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10268-69-6

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10268-69-6 Usage

Description

Phenyl Anthranilate, also known as N-Phenylanthranilic acid, is an anthranilic acid derivative with the chemical formula C13H11NO2. It is an organic compound that appears as a pale yellow solid and has a mildly sweet scent. Primarily used in the production of dyes and organic pigments, it was once popular as a sunscreen agent due to its ultraviolet light absorption capabilities. However, its use has declined due to potential health concerns. Phenyl Anthranilate is not considered hazardous or toxic in small amounts, but it may cause irritation upon contact with skin or eyes.

Uses

Used in Dye and Pigment Manufacturing:
Phenyl Anthranilate is used as a key intermediate in the synthesis of dyes and organic pigments. Its unique chemical structure allows for the creation of a wide range of colors and hues, making it valuable in various industries.
Used in Sunscreen Formulations (Historic):
Phenyl Anthranilate was once used as a sunscreen agent due to its ability to absorb ultraviolet light. However, its use in this application has decreased due to potential health concerns and the development of safer alternatives.
Used in Flavor and Fragrance Industry:
Due to its mildly sweet scent, Phenyl Anthranilate can be used in the flavor and fragrance industry to create unique aromas and tastes for various products.
Used in Research and Development:
Phenyl Anthranilate's chemical properties make it a valuable compound for research and development in the fields of chemistry, materials science, and pharmaceuticals. It can be used to study the properties of anthranilic acid derivatives and their potential applications in various industries.

Check Digit Verification of cas no

The CAS Registry Mumber 10268-69-6 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,0,2,6 and 8 respectively; the second part has 2 digits, 6 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 10268-69:
(7*1)+(6*0)+(5*2)+(4*6)+(3*8)+(2*6)+(1*9)=86
86 % 10 = 6
So 10268-69-6 is a valid CAS Registry Number.
InChI:InChI=1/C13H11NO2/c14-12-9-5-4-8-11(12)13(15)16-10-6-2-1-3-7-10/h1-9H,14H2

10268-69-6SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name Phenyl anthranilate

1.2 Other means of identification

Product number -
Other names Benzoic acid, 2-amino-, phenyl ester

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:10268-69-6 SDS

10268-69-6Relevant articles and documents

Kinetic study of hydrolysis of benzoates. Part XXV. Ortho substituent effect in alkaline hydrolysis of phenyl esters of substituted benzoic acids in water

Nummert, Vilve,Piirsalu, Mare,Maeemets, Vahur,Koppel, Ilmar

, p. 107 - 128 (2006)

The second-order rate constants k2 for alkaline hydrolysis of phenyl esters of meta-, para-and ortho-substituted benzoic acids, X-C 6H4CO2C6H5 (X = H, 3-Cl, 3-NO2, 3-CH3, 4-NO2, 4-Cl, 4-F, 4-CH 3, 4-OCH3, 4-NH2, 2-NO2, 2-CN, 2-F, 2-Cl, 2-Br, 2-I, 2-CH3, 2-OCH3, 2-CF3, 2-NH2), and of substituted phenyl esters of benzoic acid, C 6H5CO2C6H4-X (X = 2-I, 2-CF3, 2-C(CH3)3, 4-Cl, 4-CH3, 4-OCH3, 4-NH2), have been measured spectrophotometrically in water at 25 °C. The substituent effect in alkaline hydrolysis of phenyl esters of para-substituted benzoic acids, similar to that for ethyl esters of para-substituted benzoic acids, was found to be precisely described by the Hammett relationship (p = 1.7 in water). The log k value for alkaline hydrolysis of phenyl and ethyl esters of meta-, para- and ortho-substituted benzoic acids, X-C6H4CO2R, was nicely correlated with log km,p,ortho = log ko + (ρ)m,pσ + (ρI)orthoσI + (ρ° R)orthoσ°R + δ orthoΕsB where σ, σI, σ°R are the Hammett polar, Taft inductive and Taft resonance (σ°R = σ° - σI) substituent constants, respectively. Ε SB is the steric scale for ortho substituents calculated on the basis of the log k values for the acid hydrolysis of ortho-substituted phenyl benzoates in water owing to the ortho substituent in the phenyl of phenyl benzoates. In water, the main factors responsible for changes in the ortho substituent effect in alkaline hydrolysis of phenyl and ethyl esters of ortho-substituted benzoic acids, X-C6H4CO2R, were found to be the inductive and steric factors while the role of the resonance term was negligible ((ρ°R)ortho ca. 0.3). In alkaline hydrolysis of substituted benzoates in neat water, the ortho inductive effect appeared to be 1.5 times and steric influence 2.7 times higher than the corresponding influences from the ortho position in the phenyl of phenyl benzoates. The contributions of the steric effects in alkaline hydrolysis of esters of ortho-substituted benzoic acids was found to be approximately the same as in acid hydrolysis of esters of ortho-substituted benzoic and acid esterification of ortho-substituted benzoic acids.

Ruthenium(ii)-catalyzed decarbonylative and decarboxylative coupling of isatoic anhydrides with salicylaldehydes: access to aryl 2-aminobenzoates

Bora, Bidisha R.,Prakash, Rashmi,Sultana, Sabera,Gogoi, Sanjib

, p. 2725 - 2730 (2021/04/07)

A ruthenium(ii)-catalyzed coupling reaction of isatoic anhydrides and salicylaldehydes has been developed for the synthesis of 2-aminobenzoates. This reaction proceeds through metal-catalyzed decarbonylation and decarboxylation to afford good yields of aryl 2-aminobenzoates.

Studies on the Lossen-type rearrangement of N-(3-phenylpropionyloxy) phthalimide and N-tosyloxy derivatives with several nucleophiles

Chanmiya Sheikh,Takagi, Shunsuke,Ogasawara, Asako,Ohira, Masayuki,Miyatake, Ryuta,Abe, Hitoshi,Yoshimura, Toshiaki,Morita, Hiroyuki

experimental part, p. 2132 - 2140 (2010/04/26)

The reaction of N-(3-phenylpropionyloxy)phthalimide (1a) and N-tosyloxy (5a,b) derivatives with nucleophiles was examined and found to give the products via Lossen-type rearrangement. In order to obtain the scope of this reaction mechanism, further studies the reaction of several N-sulfonyloxyimide derivatives with various nucleophiles under similar conditions were carried out and found to afford the corresponding same types of products in high yields.

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