1027-86-7Relevant articles and documents
Synthesis of disilylmethanes and polysilacarbosilanes, precursors of silicon carbide-based materials
Bacque, Eric,Birot, Marc,Pillot, Jean-Paul,Lapouyade, Paulette,Gerval, Pierre,Biran, Claude,Dunogues, Jacques
, p. 99 - 107 (1996)
Using a new procedure, substituted disilylmethanes have been prepared from chlorosilanes, dichloromethane, and magnesium in tetrahydrofuran. Bis(chlorosilyl)methanes can be used as comonomers for the synthesis of polysilacarbosilanes, which are transformed into polycarbosilanes, precursors of silicon carbide.
Reactions at Silicon Centres bearing the Bulky Tris(phenyldimethylsilyl)methyl Ligand
Eaborn, Colin,Mansour, Abdulrahman I.
, p. 729 - 736 (2007/10/02)
Metallation of (PhMe2Si)3CH with MeLi in tetrahydrofuran gives (PhMe2Si)3CLi, which reacts with MeI to give (PhMe2Si)3CMe, and also with Me2SiHCl and MeSiHCl2, to give (PhMe2Si)3CSiMe2H and (PhMe2Si)3CSiMe(H)Cl, respectively, but not with Me3SiCl or a ran