Methylenebis[dimethyl(phenyl)silane]

Base Information

• Chemical Name: Methylenebis[dimethyl(phenyl)silane]
• CAS No.: 1027-86-7
• Molecular Formula: C17H24Si2
• Molecular Weight: 284.549
• DSSTox Substance ID: DTXSID50507276
• Nikkaji Number: J3.195.802D
• Wikidata: Q82363409
• Mol file: 1027-86-7.mol

Synonyms:1027-86-7;Methylenebis[dimethyl(phenyl)silane];Silane, methylenebis[dimethylphenyl- (9CI);[dimethyl(phenyl)silyl]methyl-dimethyl-phenylsilane;DTXSID50507276;{[DIMETHYL(PHENYL)SILYL]METHYL}DIMETHYLPHENYLSILANE;Si,Si,Si',Si'-tetramethyl-Si,Si'-diphenyl-Si,Si'-methanediyl-bis-silane

Chemical Property of Methylenebis[dimethyl(phenyl)silane]

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 4
• Exact Mass: 284.14165383
• Heavy Atom Count: 19
• Complexity: 243

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[Si](C)(C[Si](C)(C)C1=CC=CC=C1)C2=CC=CC=C2

Technology Process of Methylenebis[dimethyl(phenyl)silane]

There total 4 articles about Methylenebis[dimethyl(phenyl)silane] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 35.0%

dichloromethane (75-09-2) + phenyldimethylsilyl chloride (768-33-2) → bismethane (1027-86-7)

Guidance literature:

With magnesium; zinc; In tetrahydrofuran; at 40 ℃; for 90h;

DOI:10.1016/0022-328X(96)06418-2

Reference yield: 20.0%

tetrachloromethane (56-23-5) + phenyldimethylsilyl chloride (768-33-2) → bismethane (1027-86-7) + tris(phenyldimethylsilyl)methane (27628-30-4)

Guidance literature:

With magnesium; In tetrahydrofuran; at 50 ℃; for 8h; Yield given; ultrasonic bath;

Reference yield:

bis(chlorodimethylsilyl)methane (5357-38-0,124211-70-7) + phenylmagnesium bromide → bismethane (1027-86-7)

Guidance literature:

upstream raw materials:

bis(chlorodimethylsilyl)methane

tetrachloromethane

phenyldimethylsilyl chloride

dichloromethane